Fluorine-containing boronic acid ester compound and method...

Organic compounds -- part of the class 532-570 series – Organic compounds – Heterocyclic carbon compounds containing a hetero ring...

Reexamination Certificate

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Reexamination Certificate

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08044221

ABSTRACT:
A fluorine-containing boronic acid ester represented by the general formula:(R1is a linear or branched divalent aliphatic hydrocarbon group having 2 to 10 carbon atoms, R2is a hydrogen atom, an alkyl group having 1 to 3 carbon atoms or phenyl group, n is an integer of 1 to 3, and m is an integer of 0 to 4) having an improved solubility in organic solvents is produced by reacting a fluorine-containing 3,5-dihalogenoanilide derivative represented by the general formula:(R2is a hydrogen atom, an alkyl group having 1 to 3 carbon atoms or phenyl group, X is a halogen atom, n is an integer of 1 to 3, and m is an integer of 0 to 4) with a dialkoxyborane represented by the general formula:(R1is a linear or branched divalent aliphatic hydrocarbon group having 2 to 10 carbon atoms).

REFERENCES:
patent: 07-126323 (1995-05-01), None
Miyaura, Norio, et al., Palladium-Catalyzed Cross-Coupling Reactions of Organoboron Compounds,Chem. Rev., vol. 95, (1995), pp. 2457-2483.
Morgan, Alexander, et al., Synthesis, Flame-Retardancy Testing, and Preliminary Mechanism Studies of Nonhalogenated Aromatic Boronic Acids: A New Class of Condensed-Phase Polymer Flame-Retardant Additives for Acrylonitrile-Butadiene-Styrene and Polycarbonate,J. Appl. Poly. Sci., vol. 76, (2000), pp. 1257-1268.
Registry (Stn) [online], Jun. 7, 2001 [retrieval date Sep. 9, 2009] CAS registry No. 340036-45-5, 1 pg.
Registry (Stn) [online], Jun. 8, 2001 [retrieval date Sep. 9, 2009] CAS registry No. 340132-47-0, 1 pg.
International Search Report from corresponding PCT application No. PCT/JP2009/065152 dated Sep. 29, 2009, 2 pgs.
International Preliminary Report on Patentability and Written Opinion from corresponding PCT application No. PCT/JP2009/065152 dated Apr. 28, 2011, 5 pgs.

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