Polymerization catalyst composition for polymerization of...

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Polymers from only ethylenic monomers or processes of...

Reexamination Certificate

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C526S172000, C526S161000, C526S340200, C526S335000

Reexamination Certificate

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07829642

ABSTRACT:
3,4-isoprene-based polymer having high isotacticity can be produced by polymerizing an isoprene compound using a complex represented by the general formula (A) and a catalyst activator:wherein R1and R2independently represent an alkyl group, a cyclohexyl group, an aryl group or an aralkyl group; R3represents an alkyl group, an alkenyl group, an alkynyl group, an aryl group, an aralkyl group, an aliphatic, aromatic or cyclic amino group, a phosphino group, a boryl group, an alkylthio or arylthio group, or an alkoxy or aryloxy group; M represents a rare earth element selected from Sc, Y, and La to Lu with promethium (Pm) excluded; Q1 and Q2 independently represent a monoanionic ligand; L represents a neutral Lewis base; and w represents an integer of 0 to 3.

REFERENCES:
patent: 5484897 (1996-01-01), Garbassi et al.
patent: 2004/0033889 (2004-02-01), Hessen et al.
patent: 2007-161919 (2007-06-01), None
patent: WO-2005/085306 (2005-09-01), None
Bambirra et al., J. Am. Chem. Soc. 2004, 126, 9182-9183.
Suzuki et al. (JP 2007-161919 A). Jun. 2007, abstract and translation in English.
Bambirra, et al., “One Ligand Fits All: Cationic Mono(amidinate) Alkyl Catalysts over the Full Size Range of the Group 3 and Lanthanide Metals,” J.Am.Chem.Soc., vol. 126 (30), pp. 9182-9183 (2004).
Nakayama, et al., “Stereospecific Polymerizations of Conjugated Dienes by Single Site Iron Complexes Having Chelating N,N,N-Donor Ligands,” Macromolecules, vol. 36 (21), pp. 7953-7958 (2003).
Natta, et al., “Polymerization of Conjugated Diolefins by Homogeneous Aluminum Alkyl-Titanium Alkoxide Catalyst Systems,” Die Makromolekulare Chemie, Band 77, pp. 126-138 (1964).
Translation of International Preliminary Examination Report.

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