Method for activating hydrogenation catalyst and method for...

Chemistry of inorganic compounds – Oxygen or compound thereof – Peroxide

Reexamination Certificate

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C502S025000

Reexamination Certificate

active

07833510

ABSTRACT:
A method for producing hydrogen peroxide by an anthraquinone process includes the steps of: reducing with hydrogen a working solution containing an organic solvent and anthraquinone in the presence of a hydrogenation catalyst; and activating the hydrogenation catalyst when a hydrogenation selectivity has decreased due to repeated use, wherein the catalyst activation step includes a step of treating the hydrogenation catalyst with a first alkaline aqueous solution of pH 10 or above containing an alkali metal, and then washing the treated hydrogenation catalyst with water or a second alkaline aqueous solution that is more weakly alkaline than the first alkaline aqueous solution so as to set a catalyst soak solution comprising 5 parts by weight of pure water in admixture with 1 part by weight of the activated hydrogenation catalyst to a pH of 8.0 or above.

REFERENCES:
patent: 3214385 (1965-10-01), Kolyer
patent: 3780168 (1973-12-01), Käbisch
patent: 4394302 (1983-07-01), Miller et al.
patent: 6126914 (2000-10-01), Ogasawara et al.
patent: 741444 (1955-12-01), None
patent: 787340 (1957-12-01), None

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