Process for reacting polyorganosiloxanes and their use

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – From silicon reactant having at least one...

Reexamination Certificate

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C528S016000, C528S019000, C528S029000, C524S268000

Reexamination Certificate

active

07825206

ABSTRACT:
The invention provides a process for preparing SiOC-bonded polyorganosiloxanes by reacting, by processes known per se, hydroxyl-containing compounds with a stoichiometric excess of polyorganosiloxanes which contain —Si(H) units and are of the general formula (I) in the presence of one or more element compounds of main group III and/or of transition group 3 as a catalyst, wherein the reaction, on completion of conversion of the compounds containing hydroxyl groups, is continued until no further ≡Si—H groups are detectable by gas volumetric means, and also the compounds prepared in this way and their use.

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B(C6F5)3-Catalyzed Silation of alcohols: a Mild General Method for Synthesis of Silyl Ethers authored by Blackwell et al. and published in J. Org. Chem. (1999), 64, 4887-4892.

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