Dehydrogenation process intermediates

Details Dehydrogenation process intermediates Dehydrogenation process intermediates

1990-05-08

1992-05-26

Bond, Robert T.

Organic compounds -- part of the class 532-570 series

Organic compounds

Heterocyclic carbon compounds containing a hetero ring...

546 77, 546 78, C07F 704

Patent

active

051169835

ABSTRACT:
A process for dehydrogenating a compound of the formula ##STR1## which comprises reacting the compound with a silylating agent in the presence of a quinone to introduce a .DELTA..sup.1 double bond.

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patent: 4220775 (1980-09-01), Rasmussen et al.
patent: 4377584 (1983-03-01), Rasmussen et al.
Patpharma Establishment, Chem. Abstracts 94: Abs.#103680s, 103681t, 103682u, 103683v, 103684w: 779-780 (1981).
J. Am. Chem. Soc. 110: Bhattacharya, et al., 3318-3319 (1988).
Back, T. G., J. Org. Chem. 46: 1442 (1981).
Rasmussen et al., J. Med. Chem. 29: 2298 (1986).
Magnus et al., J. Am. Chem. Soc. 108: 221-227 (1986).

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