Non-aqueous electrolyte secondary battery

Chemistry: electrical current producing apparatus – product – and – Current producing cell – elements – subcombinations and... – Electrode

Reexamination Certificate

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Details

C429S218100, C429S221000, C429S223000, C429S231500, C429S232000, C429S231950, C427S058000, C427S122000

Reexamination Certificate

active

07736808

ABSTRACT:
A non-aqueous electrolyte secondary battery of the present invention includes a positive electrode including a positive electrode material mixture, a negative electrode including a negative electrode material mixture, and a non-aqueous electrolyte including a non-aqueous solvent and a first lithium salt and a second lithium salt dissolved in the non-aqueous solvent. The negative electrode material mixture includes a material capable of absorbing and desorbing lithium ions, and carbon nanofibers. The material capable of absorbing and desorbing lithium ions has a ratio A/B of a volume A in a charged state to a volume B in a discharged state of 1.2 or more. The first lithium salt is at least one selected from the group consisting of LiBF4and LiB(C2O4)2. The second lithium salt is a salt other than the first lithium salt. The first lithium salt is included in the non-aqueous electrolyte at a weight ratio of 10−4or more relative to the carbon nanofibers. The first lithium salt included in the non-aqueous electrolyte has a concentration of 0.05 mol/dm3or less.

REFERENCES:
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Shu, J., et al., “Cage-like carbon nanotubes/Si composite as anode material for lithium ion batteries,” Electrochemistry Communications, 2006, p. 51-54, vol. 8, Elsevier B.V.

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