Synthesis of anhydride containing polymers by microwave...

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Compositions to be polymerized by wave energy wherein said...

Reexamination Certificate

Rate now

  [ 0.00 ] – not rated yet Voters 0   Comments 0

Details

C522S001000, C522S077000, C522S083000, C522S162000, C522S178000, C522S176000, C522S182000, C526S072000, C526S317100, C526S318200, C526S318100, 28, 28

Reexamination Certificate

active

07659322

ABSTRACT:
The invention provides a method for preparing a polyanhydride by irradiating one or more diacids with microwave radiation in the presence of a carboxylic anhydride so as to acylate the one or more diacids to yield at least one prepolymer, and irradiating the prepolymer with microwave radiation so as to polymerize said prepolymer to yield the polyanhydride, as a homopolymer or a copolymer. High purity polyanhydrides can be prepared by this method. Reaction times compared to conventional melt polycondensations can be significantly reduced. Copolymer polyanhydrides can also be prepared by the microware radiation techniques described herein.

REFERENCES:
patent: 4888176 (1989-12-01), Langer et al.
patent: 5237032 (1993-08-01), DeMeuse et al.
patent: 6515040 (2003-02-01), Scola et al.
patent: 2002/0022675 (2002-02-01), Choi et al.
patent: 3036314 (1981-04-01), None
patent: 0266603 (1988-05-01), None
patent: 60-144331 (1985-07-01), None
patent: 63-289020 (1988-11-01), None
patent: 3-281606 (1991-12-01), None
patent: 5-306336 (1993-11-01), None
patent: 5-310907 (1993-11-01), None
patent: WO-99/02454 (1999-01-01), None
patent: WO-01/47631 (2001-07-01), None
Vogel et al “Rapid Synthesis of Polyanhydrides by Microwave Polymerization”, Macromol. Rapid Commun., 25, (online 2003), 330-333. [retrieved on Oct. 14, 2008]. Retreived from the internet:<http://www3.interscience.wiley.com/journal/106570136/issue>.
Albert, P., et al., “Comparison of Thermal and Microwave-Activated Polymerization of εCaprolactone With Titanium Tetrabutylate as Catalyst”,Macromol. Chem. Phys., 197, (1990), 1633-1641.
Anastasiou, T. J., et al., “Novel Polyanhydrides With Enhanced Thermal and Solubility Properties”,Macromolecules,33, (2000), 6217-6221.
Bedell, C., et al., “Processing and Hydrolytic Degradation of Aromatic,Ortho-Substituted Polyanhydrides”,Journal of Applied Polymer Science, 80 , (2001), 32-38.
Bucher, J. E., et al., “The Anhydrides of Isophthalic and Terephthalic Acids”,Journal of the American Chemical Society, 31(12), (1909), 1319-1321.
Campo, C. J., “Polyanhydrides: the Effects of Ring Substitution Changes on Polymer Properties”,Polymer Bulletin, 42(1), (1999), 61-68.
Carothers, W. H., “Studies of Polymerization and Ring Formation. I. An Introduction to the General Theory of Condensation Polymers”,The Journal of the American Chemical Society, 51(8), (1929),2548-2569.
Carter, K. R., “Nickel(O) Mediated Coupling Polymerizations via Microwave-Assisted Chemistry”,Macromolecules, 35(18), (2002),6757-6759.
Chiba, M., et al., “Controlled Protein Delivery From Biodegradable Tyrosine-Containing Poly(anhydride-co-imide) Microspheres”,Biomaterials, 18(13), (1997), 893-901.
Cleland, J. L., et al., “Emerging Protein Delivery Methods”,Current Opinion in Biotechnology12(2), (2001), 212-219.
Dallinger, D. , et al., “High-Throughput Synthesis ofN3-Acylated Dihydropyrimidines Combining Microwave-Assisted Synthesis and Scavenging Techniques”,Organic Letters, 5(8), (2003),1205-1208.
Domb, A. J., et al., “Absorbable Biopolymers Derived from Dimer Fatty Acids”,Journal of Polymer Science, Part A: Polymer Chemistry, 31(5), (1993), 1275-1285.
Domb, A. J., et al., “Poly(anhydrides). 3. Poly(anhydrides) Based on Aliphatic-Aromatic Diacids”,Macromolecules, 22, (1989), 3200-3204.
Domb, A. J., “Polyanhydrides. I. Preparation of High Molecular Weight Polyanhydrides”,Journal of Polymer Science: Part A: Polymer Chemistry, 25(12), (1987), 3373-3386.
Fang, X., et al., “Microwave Synthesis of Poly(ε-caprolactam-co-ε-caprolactone”,Journal of Polymer Science: Part A: Polymer Chemistry, 38, (2000), 1379-1390.
Fang, X., et al., “Ring Opening Polymerization Via Microwave Irradiation”,Book of Abstracts, 216th ACS National Meeting, (Abstract No. PMSE-279),(1998), 1 pg.
Fang, X., et al., “Ring Opening Polymerization via Microwave Irradiation”,Polymeric Materials Science and Engineering, 79, (1998), 518-519.
Fang, X. , et al., “Ring-Opening Polymerization of ε-Caprolactam and ε-Caprolactone via Microwave Irradiation”,Journal of Polymer Science: Part A: Polymer Chemistry, 40, (2002), 2264-2275.
Fu, J., et al., “New Polymeric Carriers for Controlled Drug Delivery Following Inhalation or Injection”,Biomaterials, 23(22), (2002),4425-4433.
Glass, B. M., et al., “Case Study 4-6—Rapid Parallel Synthesis Utilizing Microwave Irradiation”,In: High-Throughput Synthesis, Marcel Dekker, Inc., New York, NY,(2001), 123-128.
Gonzalez, J. I., et al., “Polyanhydride-Imides”,Die Angewandte Makromolekulare Chemie, 55(1), (1976), 85-96.
Göpferich, A. , et al., “The Influence of Microstructure and Monomer Properties on the Erosion Mechanism of a Class of Polyanhydrides”,Journal of Polymer Science, Part A: Polymer Chemistry, 31(10), (1993),2445-2458.
Griffin, A. C., et al., “Mesogenic Polymers. III. Thermal Properties and Synthesis of Three Homologous Series of Thermotropic Liquid Crystalline “Backbone” Polyesters”,Journal of Polymer Science: Polymer Physics Edition, 19, (1981), 951-969.
Hanes, J., et al., “Synthesis and Characterization of Degradable Anhydride-co-imide Teropolymers Containing Trimellitylimido-L-tyrosine: Novel Polymers for Drug Delivery”,Macromolecules, 29(16), (1996), 5279-5287.
Hill, J. W., et al., “Studies of Polymerization and Ring Formation. XIV. A Linear Superpolyanhydride and a Cyclic Dimeric Anhydride From Sebacic Acid”,The Journal of the American Chemical Society, 54(4), (Apr. 1932), 1569-1579.
Hill, J. W., et al., “Studies of Polymerization and Ring Formation. XIX. Many-Membered Cyclic Anhydrides”,The Journal of the American Chemical Society, 55(12), (Dec. 1933), 5023-5031.
Hill, J. W., et al., “Studies of Polymerization and Ring Formation. XXI. Physical Properties of Macrocyclic Esters and Anhydrides. New Types of Synthetic Masks”,Journal of the American Chemical Society, 55(12), (1933), 5039-5043.
Imai, Y., et al., “A New Facile and Rapid Synthesis of Aliphatic Polyamides by Microwave-Assisted Polycondensation of ω-Amino Acids and Nylon Salts”,Polymer Journal, 28(3), (1996), 256-260.
Imai, Y., et al., “A New Facile and Rapid Synthesis of Aliphatic Polypyromellitimides by Microwave-Assisted Polycondensation of Salt Monomers Composed of Aliphatic Diamines and Pyromellitic Acid”,Journal of Polymer Science: Part A: Polymer Chemistry, 34, (1996), 701-704.
Jiang, H. L., et al., “Preparation, Characterization and Degradation Characteristics of Polyanhydrides Containing Poly(ethylene Glycol)”,Polymer International, 48, (1999), 47-52.
Kappe, C. O., “High-Speed Combinatorial Synthesis Utilizing Microwave Irradiation”,Current Opinion in Chemical Biology, 6, (2002), 314-320.
Kaur, S., et al., “Synthesis and Characterization of a Fluorinated Polyanhydride”,Journal of Polymer Science, 40(17), (2002), 3027-3036.
Keki, S. , et al., “Fast Microwave-Mediated Bulk Polycondensation of D, L -Lactic Acids”,Macromolecular Rapid Communications, 22(13), (2001), 1063-1065.
Kieser, J., et al., “High Rate, Large Area Application of the Plasma Polymerization (PP) Process”,Proceedings of the International Ion Engineering Congress—The 7th Symposium on Ion Sources and Ion Assisted Technology(ISIAT '83) 3, (1983), 1447-1450.
Kieser, J. , et al., “Industrial Microwave Plasma Polymerization”,Thin Solid Films, 118, (1984), 203-210.
Kipper, M. J., et al., “Design of an Injectable System Based on Bioerodible Polyanhydride Microspheres for Sustained Drug Delivery”,Biomaterials, 23(22), (Nov. 2002), 4405-4412.
Koroskenyi, B., et al., “Microwave-Assisted Solvent-Free or Aqueous-Based Synthesis of B

LandOfFree

Say what you really think

Search LandOfFree.com for the USA inventors and patents. Rate them and share your experience with other people.

Rating

Synthesis of anhydride containing polymers by microwave... does not yet have a rating. At this time, there are no reviews or comments for this patent.

If you have personal experience with Synthesis of anhydride containing polymers by microwave..., we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Synthesis of anhydride containing polymers by microwave... will most certainly appreciate the feedback.

Rate now

     

Profile ID: LFUS-PAI-O-4189311

  Search
All data on this website is collected from public sources. Our data reflects the most accurate information available at the time of publication.