Process for making cation exchange membranes with enhanced elect

Chemistry: electrical and wave energy – Processes and products – Processes of treating materials by wave energy

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427115, 427243, 427337, 521 27, 521 28, 521 30, 521 33, C07C 100, B05D 512, C08J 520, C08F 520

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058765719

ABSTRACT:
A process for making a cation exchange membranes includes impregnating a film of highly fluorinated sulfonic acid polymer in sulfonyl fluoride form with a compound selected from the group having the formula R-SO.sub.2 F, wherein R is a straight chain, branched or cyclic, highly fluorinated alkyl group having 1 to 30 carbon atoms. The impregnated film is irradiated with the radiation dose being in the range of 0.1 to 15 MRad. After irradiation, the film is hydrolyzed to form the membrane. The membranes have enhanced electrochemical properties when employed in electrochemical cells including improved performance under low humidity conditions.

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