Process for producing an organometallic copolymer

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – From silicon reactant having at least one...

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528 14, 528 17, 528 31, 528 39, 528 10, 528 33, 528 35, C08G 7750, C08G 7760

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044554141

ABSTRACT:
A process for producing an organometallic copolymer composed of a polycarbosilane portion and a polymetallosiloxane portion crosslinked with each other, which comprises reacting (1) a polycarbosilane having a main chain skeleton composed mainly of carbosilane units of the formula --Si--CH.sub.2 --, with (2) a polymetallosiloxane having a main chain skeleton composed of metalloxane units of the formula --M--O-- wherein M represents Ti or Zr and siloxane units of the formula --Si--O--, in an organic solvent in an inert atmosphere thereby to bond at least some of the silicon atoms of said polycarbosilane to at least some of the metal atoms M and/or silicon atoms of said polymetallosiloxane through an oxygen atom; and the organometallic copolymer obtained by the aforesaid process.

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patent: 4159259 (1979-06-01), Yajima et al.

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