Electron mediator, electron mediator immobilized electrode,...

Chemistry: electrical current producing apparatus – product – and – Having earth feature

Reexamination Certificate

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C204S242000, C204S403100, C204S403140, C205S777500, C429S010000, C429S047000, C435S174000, C435S175000, C435S180000, C435S181000, C435S817000

Reexamination Certificate

active

07544438

ABSTRACT:
An object of the present invention is to provide a highly functional mediator capable of smoothly proceeding electron transfer between an electrode and a biocatalyst based on the premise that the mediator excels in safety and cost and to provide an electrode and a cell with sufficient amount of such a mediator molecule immobilized efficiently and strongly. The present invention provides a mediator mediating electron transfer between an enzyme and an electrode and containing a quinone molecule derivative, in particular, a mediator containing a VK3derivative. In addition, the present invention provides an electrode and a biofuel cell to which those mediators are applied.

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Cheng, et al,; “Development of dimethyl sulfoxide biosensor using a mediator immobilized enzyme electrode”; (2003);The Analyst;full paper.
Wang, et al.; “Oxygen-independent poly(dimethylsiloxane)-based carbon-paste glucose biosensors”; (2002);Biosensors and Bioelectronics;17: 999-1003.
Miki, et al.; “Bioelectrocatalysis at NAD-Dependent Dehydrogenase and Diaphorase-Modified Carbon Paste Electrodes Containing Mediators”; (1989);Analytical Sciences;vol. 5, pp. 269-274.
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