Polymerization process using metallocene catalyst systems

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Polymers from only ethylenic monomers or processes of...

Reexamination Certificate

Rate now

  [ 0.00 ] – not rated yet Voters 0   Comments 0

Details

C526S129000, C526S160000, C526S943000, C502S120000, C502S152000

Reexamination Certificate

active

07579415

ABSTRACT:
The present invention relates to a polymerization process using improved metallocene catalyst systems. Specifically, the catalyst systems of the present invention relate to a metallocene compound having optimized metals loading and activator concentration, and demonstrate improved operability and productivity. In an exemplary embodiment, the improved metallocene catalyst system of the present invention comprises a metallocene catalyst compound activated by methylaluminoxane, and a support material, the methylaluminoxane being present in the range of from 3 to 9 mmole methylaluminoxane per gram of support material, and the metallocene being present in the range of from 0.01 to 1.0 mmole metallocene per gram of support material.

REFERENCES:
patent: 3248179 (1966-04-01), Norwood
patent: 4271060 (1981-06-01), Hubby
patent: 4613484 (1986-09-01), Ayres et al.
patent: 5001205 (1991-03-01), Hoel
patent: 5026798 (1991-06-01), Canich
patent: 5236998 (1993-08-01), Lundeen et al.
patent: 5283278 (1994-02-01), Daire et al.
patent: 5589555 (1996-12-01), Zboril et al.
patent: 5595950 (1997-01-01), Sagar et al.
patent: 5665818 (1997-09-01), Tilston et al.
patent: 5677375 (1997-10-01), Rifi et al.
patent: 5703187 (1997-12-01), Timmers
patent: 5747406 (1998-05-01), Reichle et al.
patent: 5763547 (1998-06-01), Kolthammer et al.
patent: 6015766 (2000-01-01), Kissin
patent: 6048817 (2000-04-01), Sagae et al.
patent: 6069213 (2000-05-01), Nemzek et al.
patent: 6090740 (2000-07-01), Agapiou et al.
patent: 6107230 (2000-08-01), McDaniel et al.
patent: 6153551 (2000-11-01), Kissin et al.
patent: 6165929 (2000-12-01), McDaniel et al.
patent: 6180731 (2001-01-01), Rohde et al.
patent: 6245705 (2001-06-01), Kissin
patent: 6265339 (2001-07-01), Bidell et al.
patent: 6300271 (2001-10-01), McDaniel et al.
patent: 6300436 (2001-10-01), Agapiou et al.
patent: 6355594 (2002-03-01), McDaniel et al.
patent: 6395666 (2002-05-01), McDaniel et al.
patent: 6423663 (2002-07-01), Debras
patent: 6444763 (2002-09-01), Sagae et al.
patent: 6482901 (2002-11-01), Debras
patent: 6486089 (2002-11-01), Kissin et al.
patent: 6489428 (2002-12-01), Debras et al.
patent: 6521728 (2003-02-01), Diefenbach
patent: 6531550 (2003-03-01), McDaniel et al.
patent: 6548441 (2003-04-01), McDaniel et al.
patent: 6548442 (2003-04-01), McDaniel et al.
patent: 6583240 (2003-06-01), Wang et al.
patent: 6608153 (2003-08-01), Agapiou et al.
patent: 7132382 (2006-11-01), McCullough et al.
patent: 7244795 (2007-07-01), Agapiou et al.
patent: 2002/0007023 (2002-01-01), McDaniel et al.
patent: 2002/0032287 (2002-03-01), McCullough
patent: 2002/0082365 (2002-06-01), McDaniel et al.
patent: 2002/0128404 (2002-09-01), McDaniel et al.
patent: 2003/0120002 (2003-06-01), McDaniel et al.
patent: 0 511 665 (1992-11-01), None
patent: 0 767 184 (1997-04-01), None
patent: 0 794 200 (1997-09-01), None
W. Kaminsky, et al., “Fluorinated Half-Sandwich Complexes as Catalysts in Syndiospecific Styrene Polymerization,” Macromolecules, American Chemical Society, vol. 30, No. 25, pp. 7648-7650, Dec. 15, 1997.
Axel Herzog, et al., “Reactions of (η5-C5Me5)ZrF3, (η5-C5Me4Ee)ZrF3. (η5-C5Me5)2ZrF2. (η5-C5Me5)HfF3. and (η5-C5Me5)TaF4with AIMe3. Structure of the First Hafnium-Aluminum-Carbon Cluster,” Organometallics, vol. 15, No. 3, pp. 909-917, Jul. 31, 1995.
Eamonn F. Murphy, et al., “Synhesis and Spectroscopic Characterization of a Series of Substituted Cyclopent Adienyl Group 4 Fluorides; Crystal Structure of the Acetylacetonato Complex [(ACAC)2(η5-C5Me5)Zr(μ-F)SnMe3C1],” Dalton, Paper 5/07747H, Nov. 28, 1995.
F. Garbassi, et al., “XPS Study of Metallocene Based Catalysts for the Polymerization of Ethylene,” Journal of Molecular Catalysts A: Chemical 101 (1995) 190-209, Mar. 1995.
Walter Kaminsky, “Highly Active Metallocene Catalysts for Olefin Polymerization,” J. Chem. Soc., Dalton Trans., pp. 1413-1418, 1998.
Eamonn F. Murphy, et al., “Organometallic Fluorides: Compounds Containing Carbon-Metal-Fluorine Fragments of D-Block Metals,” American Chemical Society, Chem. Rev. 1997, 97, pp. 3425-3468, Jun. 4, 1997 Revised Sep. 15, 1997.

LandOfFree

Say what you really think

Search LandOfFree.com for the USA inventors and patents. Rate them and share your experience with other people.

Rating

Polymerization process using metallocene catalyst systems does not yet have a rating. At this time, there are no reviews or comments for this patent.

If you have personal experience with Polymerization process using metallocene catalyst systems, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Polymerization process using metallocene catalyst systems will most certainly appreciate the feedback.

Rate now

     

Profile ID: LFUS-PAI-O-4117917

  Search
All data on this website is collected from public sources. Our data reflects the most accurate information available at the time of publication.