Process for the manufacture of peroxycarboxylic acids

Details Process for the manufacture of peroxycarboxylic acids Process for the manufacture of peroxycarboxylic acids

1977-03-28

1979-10-23

Konopka, P. E.

Chemistry of carbon compounds

Miscellaneous organic carbon compounds

C-metal

260413, 260502R, C11C 300, C07C17910

Patent

active

041720865

ABSTRACT:
Peroxycarboxylic acids are prepared by the oxidation of a fatty acid with an excess of hydrogen peroxide in the presence of a strong acid catalyst. The yield is improved and the reaction time is reduced by intimately dispersing throughout the reaction mixture an inert water immiscible solvent for the peroxycarboxylic acid. The product may be recovered in crystalline form from the solvent phase.

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Aliphatic Diperacids; W. E. Parker et al.; J.A.C.S. 79, 1929-1931 (1957).
New Method for the Direct Preparation of Aromatic & Aliphatic Peroxy Acids; L. S. Silbert et al., J. Org. Chem., 27, 1336-1342 (1962).

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