Siloxane polymers with quadruple hydrogen bonding units

Drug – bio-affecting and body treating compositions – Preparations characterized by special physical form – Cosmetic – antiperspirant – dentifrice

Reexamination Certificate

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C424S065000, C424S070120, C424S078020, C528S010000

Reexamination Certificate

active

07622131

ABSTRACT:
The invention relates to the synthesis of siloxane polymers containing self-complementary quadruple hydrogen bonding groups (4H-units). The resulting polymers show unique new characteristics that result from the reversible, physical interactions between the polysiloxane chains that are based on the (supramolecular) interactions between the 4H-units. The polysiloxanes in this invention show unprecedented bulk material properties and are used as gelling agents for silicone fluids. The resulting gels are clear and display good material properties, while having unparalleled high silicone fluid contents.

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Sijbesma et al., “Reversible Polymers formed from Self-Complementary Monomers Using Quadruple Hydrogen Bonding”, Nov. 28, 1997, Science, vol. 278, pp. 1601-1604, USA.
Folmer et al., “Supramolecular Polymer Materials: Chain Extension of Telechelic Polymers Using a Reactive Hydrogen-Bonding Synthon”, Adv. Materials, 2000, vol. 12, No. 12, pp. 874-878, Germany.
Hirschberg et al., Supramolecular Polymers from Linear Telechelic Siloxane with Quadruple-Hydrogen-Bonded Units, Macromolecules, 1999, vol. 32, pp. 2696-2705, USA.

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