Zinc lanthanide sulfonic acid electrolytes

Compositions – Electrically conductive or emissive compositions

Reexamination Certificate

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C252S512000, C252S518100, C252S519500, C205S064000, C429S101000, C429S105000, C429S229000

Reexamination Certificate

active

07452486

ABSTRACT:
Disclosed are aqueous solutions for use in high energy, highly efficient electrical energy storage devices. The solutions contain (a) a high purity sulfonic acid with a low concentration of low valent sulfur compounds or higher valent sulfur compounds susceptible to reduction, (b) a metal or metals in an oxidized state that are capable of being reduced to the zero valent oxidation state, (c) a metal that is in an oxidized state that is incapable of being reduced to its metallic state and (d) optionally, a buffering agent and/or conductivity salts.

REFERENCES:
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patent: 2525943 (1950-10-01), Proell
patent: 4639298 (1987-01-01), Kreh et al.
patent: 4647349 (1987-03-01), Kreh et al.
patent: 4670108 (1987-06-01), Kreh et al.
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patent: 2006/0272950 (2006-12-01), Martyak et al.
patent: 0786539 (1997-07-01), None
patent: 11-200088 (1999-07-01), None
patent: WO 03/017395 (2003-02-01), None
Proell, et al, Monthly Review of the American Electroplaters Society,“Copper Plating in Alkanesulfonic Acid Baths,” 1947, vol. 34, pp. 541-549.
Clarke, et al, “Introducing Cerium Based High Energy Redox Batteries,” ESAT Conference, San Francisco, CA, Apr. 15-17, 2002, pp. 1-6.

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