Process for preparing a film having alternating monolayers...

Coating processes – With post-treatment of coating or coating material – Plural film forming coatings wherein one coating contains a...

Reexamination Certificate

Rate now

  [ 0.00 ] – not rated yet Voters 0   Comments 0

Details

C427S404000, C427S405000, C427S407100, C427S409000, C427S412100, C427S419300, C427S419500, C427S419700, C427S419800

Reexamination Certificate

active

07445815

ABSTRACT:
The present invention provides a process for preparing a thin film having alternating monolayers of a metal-metal bonded complex monolayer and an organic monolayer by layer-by-layer growth. The process comprises the steps of: (1) applying onto a surface of a substrate a first linker compound to produce a primer layer; (2) applying onto said primer layer a layer of a metal-metal bonded complex to produce a metal-metal bonded complex monolayer on said primer layer;(3) applying onto said metal-metal bonded complex monolayer a second linker compound; and optionally(4) sequentially repeating steps (2) and (3) at least once to produce said layer-by-layer grown thin film having alternating monolayers of a metal-metal bonded complex monolayer and an organic monolayer.

REFERENCES:
patent: 5217792 (1993-06-01), Chidsey et al.
patent: 5326626 (1994-07-01), Chidsey et al.
patent: 6128214 (2000-10-01), Kuckes et al.
patent: 6198655 (2001-03-01), Heath et al.
patent: 6314019 (2001-11-01), Kuekes et al.
patent: 6479240 (2002-11-01), Kayyem et al.
patent: 6646285 (2003-11-01), Kagan et al.
patent: 2001/0054709 (2001-12-01), Heath et al.
patent: 2002/0121314 (2002-09-01), Tao et al.
“One-Dimensional Polymers and Mesogens Incorporating Multiple Bonds Between Metal Atoms”, Chisholm,Amernican Chemical Society2000.
“Synthesis and Antitumor ‘Activity’ of certain Rhodium (II) Carboxylates”, Hall et al.,Institute of Molecular Medicine, vol. 10, No. 1, 1980.
“Chiral Dirhidium Carboxamidates: Catalysts for Highly Enantioselective Syntheses of Lactones and Lactams” Doyle, Trinity University, date unknown.
“The Chemistry of Multielectron Excited States” Nocera,American Chemical Society, 1995.
“Layered Metal Phosphates and Phosphates: From Crystals to Monolayers” Cao et al.,American Chemical Society1992.
“Fuzzy Nanoassemblies: Toward Layered Polyermic Multicomposites”, Decher, www.sciencemag.gov, vol. 277, Aug. 29, 1997.
“Coordinate Covalent Cobalt-Diisocyanide Multilayer Thin Films Grown One Molecular Layer at a time”, Ansell et al.,American Chemical Society, Nov. 27, 1999.
“Synthesis and Proton-Coupled Electron-Transfer Reaction of Self-Assembled Monolayers of a Ruthenium (II) Complex Containing Tridentate 2,6-Bis(benzimidazol-2-yl)pryridine on a Gold Surface: Comparison of Acid/Base Chemistry with Bulk Solution Chemistry,” Haga et al.,Inorg. Chem.2000, 39, pp. 4566-4573, published on web Sep. 13, 2000.
“Photostability, Electrochemistry, and Monolayers of [M(bpy)2(trans-1,2-bis(4-pyridyl)ethylene)L]+(M=Ru, Os; L=Cl, H2O)”, Forster et al.,Langmuir2000, 16, pp. 7867-7870, published on web Aug. 31, 2000.
“Electron Transfer Reactions of Self-Assembled Monolayers of Thio(Phenylacetylene)n-Substituted Chiral Metal-Salen Complexes”, Nielsen et al.Langmuir2002, 18, pages 2795-2799, published on web Feb. 23, 2002.
“XPS Study of Self-Assembly of Ruthenium Dimers [((acac)2Ru)2bptz]0,+on Hydrophobic and Hydrophilic SAMs,” Varughese et al.,Langmuir, 2002, 18, pp. 7964-7970, published on web Sep. 21, 2002.

LandOfFree

Say what you really think

Search LandOfFree.com for the USA inventors and patents. Rate them and share your experience with other people.

Rating

Process for preparing a film having alternating monolayers... does not yet have a rating. At this time, there are no reviews or comments for this patent.

If you have personal experience with Process for preparing a film having alternating monolayers..., we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Process for preparing a film having alternating monolayers... will most certainly appreciate the feedback.

Rate now

     

Profile ID: LFUS-PAI-O-4048431

  Search
All data on this website is collected from public sources. Our data reflects the most accurate information available at the time of publication.