Stabilization of polyolefins with liquid...

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Processes of preparing a desired or intentional composition...

Reexamination Certificate

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C524S585000, C524S587000

Reexamination Certificate

active

07468410

ABSTRACT:
The present invention discloses a process for stabilizing polyolefin compositions against the deleterious effects of melt processing, heat aging and exposure to combustion products of natural gas, which process comprises incorporating or applying to a polyolefin an effective stabilizing amount of a tris-(mono-alkyl)phenyl phosphite ester of the formula I,or a mixture of phosphite esters of formula I, where each R is the same or different and is straight or branched chain alkyl of from 1 to 8 carbon atoms, and where said phosphite ester or phosphite ester mixture is in the liquid state at 25° C. and 1 atm of pressure. Also disclosed is a stabilized composition comprising polyolefin and a present phosphite ester or phosphite ester mixture as well as certain mixtures of tris-(mono-alkyl)phenyl phosphite. The present liquid phosphite ester stabilizers are especially compatible with low density polyethylene.

REFERENCES:
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patent: 3644536 (1972-02-01), Bafford
patent: 3756906 (1973-09-01), Leyland et al.
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patent: 6576788 (2003-06-01), Penzel et al.
patent: 2940620 (1981-04-01), None
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patent: 1298248 (1972-11-01), None
patent: 2227490 (1990-08-01), None
patent: 7309884 (1995-11-01), None
Plastics Additives Handbook, 4thEd., R. Gächter, H. Müller, Eds., 1993, pp. 40-71.
The Thompson Corp. on STN, Abstract No. 1981-29234D for DE 2940620, Apr. 16, 1981.
English Abstract for JP 7309884, Nov. 28, 1995.

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