Alkyllithium compounds containing cyclic amines and their use in

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Polymers from only ethylenic monomers or processes of...

Patent

Rate now

  [ 0.00 ] – not rated yet Voters 0   Comments 0

Details

526204, 526217, 540450, 540465, 540482, 540484, 540541, 540605, 540612, C07D22306, C07D22706, C08F 448

Patent

active

057928207

ABSTRACT:
An organolithium compound according to the present invention containing a cyclic amino group, has the general formula: ##STR1## wherein R.sub.1 is a divalent alkylene, an oxy- or amino-alkylene, or substituted alkylene having from 6 to about 20 carbon atoms; R.sub.2 is a linear-, branched-, or cyclo-alkylene having from about 2 to about 20 carbon atoms; and the lithium, Li, is bonded directly to a carbon atom of R.sub.2. A method of preparing an organolithium compound containing a cyclic amino group, comprising reacting a cyclic amino organo halide having the general formula ##STR2## where R.sub.1 and R.sub.2 are as above, and X is bromine or chlorine bonded directly to a carbon atom of R.sub.2, with a lithium reactant selected from lithium metal or an organolithium compound.

REFERENCES:
patent: 2849432 (1958-08-01), Kibler et al.
patent: 3109871 (1963-11-01), Zalinski et al.
patent: 3177190 (1965-04-01), Hsieh
patent: 3178398 (1965-04-01), Strobel et al.
patent: 3240772 (1966-03-01), Natta et al.
patent: 3290277 (1966-12-01), Anderson et al.
patent: 3317918 (1967-05-01), Foster
patent: 3326881 (1967-06-01), Uraneck et al.
patent: 3331821 (1967-07-01), Strobel
patent: 3393182 (1968-07-01), Trepka
patent: 3426006 (1969-02-01), Nutzel et al.
patent: 3439049 (1969-04-01), Trepka
patent: 3856877 (1974-12-01), Otsuki et al.
patent: 3935177 (1976-01-01), Muller et al.
patent: 4015061 (1977-03-01), Schulz et al.
patent: 4026865 (1977-05-01), Uraneck et al.
patent: 4085265 (1978-04-01), Otsuki et al.
patent: 4247418 (1981-01-01), Halasa et al.
patent: 4316001 (1982-02-01), Boileau et al.
patent: 4383085 (1983-05-01), Fujimaki et al.
patent: 4414372 (1983-11-01), Farnham et al.
patent: 4429091 (1984-01-01), Hall
patent: 4476240 (1984-10-01), Hall et al.
patent: 4478953 (1984-10-01), Yuki et al.
patent: 4515922 (1985-05-01), Sakakibara et al.
patent: 4614771 (1986-09-01), Watanabe et al.
patent: 4616069 (1986-10-01), Watanabe et al.
patent: 4647634 (1987-03-01), Jalics
patent: 4677153 (1987-06-01), Kitahara et al.
patent: 4734461 (1988-03-01), Roggero et al.
patent: 4735994 (1988-04-01), Rogger et al.
patent: 4736003 (1988-04-01), Schneider et al.
patent: 4791174 (1988-12-01), Bronstert et al.
patent: 4816520 (1989-03-01), Bronstert
patent: 4835209 (1989-05-01), Kitagawa et al.
patent: 4843120 (1989-06-01), Halasa et al.
patent: 4894409 (1990-01-01), Shimada et al.
patent: 4914147 (1990-04-01), Mouri et al.
patent: 4931376 (1990-06-01), Ikematsu et al.
patent: 4935471 (1990-06-01), Halasa et al.
patent: 4978754 (1990-12-01), Ibi et al.
patent: 5066729 (1991-11-01), Stayer, Jr. et al.
patent: 5112929 (1992-05-01), Hall
patent: 5115035 (1992-05-01), Shiraki et al.
patent: 5149457 (1992-09-01), Smith
patent: 5153159 (1992-10-01), Antkowiak et al.
patent: 5173209 (1992-12-01), Smith, Jr. et al.
patent: 5238893 (1993-08-01), Hergenrother et al.
patent: 5292790 (1994-03-01), Shimizu et al.
patent: 5329005 (1994-07-01), Lawson et al.
patent: 5332810 (1994-07-01), Lawson et al.
patent: 5393721 (1995-02-01), Kitamura et al.
patent: 5523364 (1996-06-01), Engel et al.
patent: 5527753 (1996-06-01), Engel et al.
patent: 5550203 (1996-08-01), Engel et al.
"3-Dimethylaminopropyl-Lithium--An Analytical and Kinetic Investigation of a New Initiator System for Polymer Synthesis" by Eisenbach et al., European Patent Journal, vol. 11, pp. 699-704 (1975).
"A Bifunctional Anionic Initiator Soluble in Non-polar Solvents" by Beinert et al., Makromol. Chem 179, pp. 551-555 (1978).
"An improved synthesis of p-dimethylaminophenyl-lithium" by Hallas et al., Chemistry and Industry, p. 620 (1969).
"Anionic Polymerization. VII Polymerization and Copolymerization with Lithium Nitrogen-Bonded Initiator" by Cheng, American Chemical Society, pp. 513-528 (1981).
"Anionic Polymerization Initiators Containing Protected Functional Groups and Functionally Terminated Diene Polymers" by Schulz et al., Journal of Polymer Science: Polymer Chemistry Edition, vol. 12, pp. 153-166 (1974).
"Anionic Polymerization Initiated by Diethylamide in Organic Solvents. I. The Use of Lithium Diethylamide as a Polymerization Catalyst and the Effect of Solvent Type on the Polymerization of Isoprene and Styrene" by Angood et al., Journal of Polymer Science: Polymer Chemistry Edition, vol. 11, pp. 2777-2791 (1973).
"Anionic Polymerization Initiators Containing Protected Functional Groups. II." by Schulz et al., Journal of Polymer Science: Polymer Chemistry Edition, vol. 15, pp. 2401-2410 (1977).
"Bifunctional anionic initiators: A critical study and overview" by Bandermann et al., Makromol. Chem 186, pp. 2017-2024 (1985).
"Butadiene-Styrene Copolymerization Initiated by n-BuLi/THF/t-AmOK", by Lehong et al., Journal of Applied Polymer Science, vol. 44, pp. 1499-1505 (1992).
"6001 Chemical Abstracts", vol. 91, p. 59 (1979).
"Copolymerization of Butadiene and Styrene by Initiation with Alkyllithium and Alkai Metal tert-Butoxides" by Wofford et al., Journal of Polymer Science: Part A-1, vol. 7, pp. 461-469 (1969).
"Lithium Amide Catalyzed Amine-Olefin Addition Reactions" by Schlott et al., J. Org. Chem., vol. 37, No. 26, pp. 4243-4245 (1972).
"New perfectly difunctional organolithium initiators for block copolymer synthesis: Synthesis of dilithium initiators in the absence of polar additives", by Guyot et al., Polymer, vol. 22 (1981).
"Polymerization of Unsaturated Compounds in the Presence of Lithium Diethylamide" by Vinogradov et al., Polymer Science U.S.S.R., vol. 4, pp. 1568-1572 (1963).
"Ortho Lithiation via a Carbonyl Synthon" by Harris et al., J. Org. Chem., vol. 44, No. 12, pp. 2004-2006 (1979).
"Preparation and Reactions of Trialkyltinlithium" by Tamborski et al., pp. 237-239, Jan. 1963.
"Preparation of Some Trialkyltin-lithium Compounds" by Gilman et al., J. Am. Chem. Soc. 75, pp. 2507-2509 (1953).
"Some Reactions of Tributyl- and Triphenyl-stannyl Derivatives of Alkali Metals" by Blake et al., J. Chem. Soc., pp. 618-622, (1961).
"Specific Functionalization of Polymers by Carboxyl Groups" by Broze et al., Makromol. Chem. 179, pp. 1383-1386 (1978).
"Stereospecific Addition Reaction Between Butadiene and Amines" by Imai et al., Tetrahedron Letters No. 38, pp. 3317-3520 (1971).
"Studies of the Anionic Polymerization of Phenyl Vinyl Sulfoxide and Its Copolymer with Styrene" by Kanga et al. Macromolecules 23, pp. 4235-4240 (1990).
"Synthesis of New Monomers by Addition Reactions of Diethylamine to 1,4-Divinylbenzene Catalyzed by Lithium Diethylamide" by Tsuruta et al., Makromol. Chem. 177, pp. 3255-3263 (1976).
"The Microstructure of Butadiene and Styrene Copolymers Sythesized with n-BuLi/THF/t-AmOK" by Lehong et al., Journal of Applied Polymer Science, vol. 44, pp. 1507-1511 (1992).
"Thermal Elimination of Poly(phenyl vinyl sulfoxide) and Its Polystyrene Block Copolymers" by Kanga et al., Macromolecules 23, pp. 4241-4246 (1990).
"Metalations of Benzyldimethylamine and Related Amines with n-Butyllithium in Ether. Deuteration to Form Ring and Side-chain Derivatives" by Jones et al., J. Org. Chem. 23, 663 (Mar. 1963) pp. 663-665.

LandOfFree

Say what you really think

Search LandOfFree.com for the USA inventors and patents. Rate them and share your experience with other people.

Rating

Alkyllithium compounds containing cyclic amines and their use in does not yet have a rating. At this time, there are no reviews or comments for this patent.

If you have personal experience with Alkyllithium compounds containing cyclic amines and their use in, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Alkyllithium compounds containing cyclic amines and their use in will most certainly appreciate the feedback.

Rate now

     

Profile ID: LFUS-PAI-O-389643

  Search
All data on this website is collected from public sources. Our data reflects the most accurate information available at the time of publication.