Processes for producing oxide with higher oxidation than...

Details Processes for producing oxide with higher oxidation than... Processes for producing oxide with higher oxidation than...

2007-02-27

2007-02-27

McKenzie, Thomas (Department: 1625)

Organic compounds -- part of the class 532-570 series

Organic compounds

Heterocyclic carbon compounds containing a hetero ring...

C549S295000, C549S307000, C560S239000, C562S409000, C568S322000, C568S426000, C568S485000

Reexamination Certificate

active

10915600

ABSTRACT:
The present invention provides a process for producing an oxide from an alcohol compound, the process comprising the steps of causing silica gel to carry the alcohol compound thereon and an oxidative catalyst thereon, and oxidizing the alcohol compound in the presence of an oxidizing agent, giving an oxide higher in oxidizing degree than the alcohol compound, and also provides a process for producing an oxide from an alcohol compound, the process comprising the steps of causing silica gel to carry the alcohol compound, and subjecting the alcohol compound to an electrolytic oxidation, giving an oxide higher in oxidizing degree than the alcohol compound.

REFERENCES:
patent: 05-02507 (1993-02-01), None
patent: 06-211827 (1994-08-01), None
Inokuchi et al , Indirect Electrooxidation of Alcohols by a double Mediatory System, J. Org. Chem. vol. 56 pp. 2416-2421 (1991).
Bobbitt et al, J. Org. Chem. vol. 63 pp. 9367-9374 (1998).
Inokuchi, T. et al.; “Indirect Electrooxidation of Alcohols by a Double Mediatory System with Two Redox Couples of [R2N4=O]/R2NO and {Br or Br+]/Br in an Organic-Aqueous Two-Phase Solution”;J. Org. Chem; vol. 56, pp. 2146-2421; 1991.
Bobbitt et al., J. Org. Chem, vol. 63, pp. 9367-9374 (1998).

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