Mono- and Di(functionally-substituted phenylene) semi-rigid crow

Organic compounds -- part of the class 532-570 series – Organic compounds – Heterocyclic carbon compounds containing a hetero ring...

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549351, C07D32100

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active

051420686

ABSTRACT:
Bis(carboalkoxy-substituted m-phenylene)-32-crown-10 compounds, useful as polymerizable monomers, can be formed in one step by reacting a functionalized dihydroxy aromatic compound with a dihalopolyether. In the same reaction, carboalkoxy-substituted m-phenylene-16-crown-5 is formed. Other mono- and di-functionalized bis(phenylene) crown ethers can be made by one step as well as multistep synthesis from similar starting materials.

REFERENCES:
patent: 4777270 (1988-10-01), Urban
patent: 5028721 (1991-07-01), Gibson et al.
Moore, S. et al. "Host Guest Complexation. 4. Remote Substituent Effects on Nacrocyclic Polyether Binding to Metal and Ammonium ions" JACS 99:19 pp. 6398-6405 (1977).
Chapoteau, E. et al. "Synthesis, Structures and Complexing Abilities of Corands Based on 2-Methoxyresoicinol" J. Org. Chem. 54:4 pp. 861-867 (1989).

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