Solid polymer electrolyte and method of preparation

Chemistry: electrical current producing apparatus – product – and – Current producing cell – elements – subcombinations and... – Include electrolyte chemically specified and method

Reexamination Certificate

Rate now

  [ 0.00 ] – not rated yet Voters 0   Comments 0

Details

C429S313000, C429S317000

Reexamination Certificate

active

10496230

ABSTRACT:
Disclosed is an improved solid electrolyte made of an interpenetrating network type solid polymer comprised of two compatible phases: a crosslinked polymer for mechanical strength and chemical stability, and an ionic conducting phase. The highly branched siloxane polymer of the present invention has one or more poly(ethylene oxide) (“PEO”) groups as a side chain. The PEO group is directly grafted to silicon atoms in the siloxane polymer. This kind of branched type siloxane polymer is stably anchored in the network structure and provides continuous conducting paths in all directions throughout the IPN solid polymer electrolyte. Also disclosed is a method of making an electrochemical cell incorporating the electrolyte. A cell made accordingly has an extremely high cycle life and electrochemical stability.

REFERENCES:
patent: 3172899 (1965-03-01), Bailey
patent: 3734876 (1973-05-01), Chu
patent: 4259467 (1981-03-01), Keogh et al.
patent: 4830939 (1989-05-01), Lee et al.
patent: 4849856 (1989-07-01), Funari et al.
patent: 4908283 (1990-03-01), Takahashi et al.
patent: 5037712 (1991-08-01), Shackle et al.
patent: 5112512 (1992-05-01), Nakamura
patent: 5272021 (1993-12-01), Asai et al.
patent: 5300375 (1994-04-01), Chaloner-Gill
patent: 5362493 (1994-11-01), Skotheim et al.
patent: 5419984 (1995-05-01), Chaloner-Gill et al.
patent: 5475127 (1995-12-01), Klein et al.
patent: 5538812 (1996-07-01), Lee et al.
patent: 5593787 (1997-01-01), Dauth et al.
patent: 5609974 (1997-03-01), Sun
patent: 5633098 (1997-05-01), Narang et al.
patent: 5690702 (1997-11-01), Skotheim et al.
patent: 5700300 (1997-12-01), Jensen et al.
patent: 5731104 (1998-03-01), Ventura et al.
patent: 5753389 (1998-05-01), Gan et al.
patent: 5772934 (1998-06-01), MacFadden
patent: 5882812 (1999-03-01), Visco et al.
patent: 5885733 (1999-03-01), Ohsawa et al.
patent: 5919587 (1999-07-01), Mukherjee et al.
patent: 5961672 (1999-10-01), Skotheim et al.
patent: 6013393 (2000-01-01), Taniuchi et al.
patent: 6015638 (2000-01-01), Ventura et al.
patent: 6124062 (2000-09-01), Horie et al.
patent: 6168885 (2001-01-01), Narang et al.
patent: 6181545 (2001-01-01), Amatucci et al.
patent: 6245465 (2001-06-01), Angell et al.
patent: 6248481 (2001-06-01), Visco et al.
patent: 6252762 (2001-06-01), Amatucci
patent: 6268088 (2001-07-01), Oh et al.
patent: 6337383 (2002-01-01), West et al.
patent: 6447952 (2002-09-01), Spiegel et al.
patent: 6482912 (2002-11-01), Boudjouk et al.
patent: 6495287 (2002-12-01), Kolb et al.
patent: 6573009 (2003-06-01), Noda et al.
patent: 6610109 (2003-08-01), Noh
patent: 6653015 (2003-11-01), Yoshida et al.
patent: 2002/0028388 (2002-03-01), Lee
patent: 2002/0051911 (2002-05-01), Okada
patent: 2002/0192554 (2002-12-01), Woo et al.
patent: 2003/0036003 (2003-02-01), Shchori et al.
patent: 2003/0099884 (2003-05-01), Chiang et al.
patent: 2003/0104282 (2003-06-01), Xing et al.
patent: 2003/0198869 (2003-10-01), West et al.
patent: 0 450 981 (1991-10-01), None
patent: 0 525 728 (1993-02-01), None
patent: 0 581 296 (1994-02-01), None
patent: 0 581 296 (1994-02-01), None
patent: 0 922 049 (1998-02-01), None
patent: 0 932 215 (1999-01-01), None
patent: 0 796 511 (1999-08-01), None
patent: 1 024 502 (2000-08-01), None
patent: 0 932 215 (2001-05-01), None
patent: 1 202 374 (2002-05-01), None
patent: 57-034662 (1982-02-01), None
patent: 57-080670 (1982-05-01), None
patent: 57-111957 (1982-07-01), None
patent: 57-176669 (1982-10-01), None
patent: 59-224072 (1984-12-01), None
patent: 60-195877 (1985-10-01), None
patent: 60-216461 (1985-10-01), None
patent: 61-288374 (1986-12-01), None
patent: 62-209169 (1987-09-01), None
patent: 63-010466 (1988-01-01), None
patent: 63-310569 (1988-12-01), None
patent: 02-080462 (1990-03-01), None
patent: 02-262274 (1990-10-01), None
patent: 02-291603 (1990-12-01), None
patent: 03-139566 (1991-06-01), None
patent: 60-052893 (1992-07-01), None
patent: 05-036441 (1993-02-01), None
patent: 05-290616 (1993-11-01), None
patent: 08-078053 (1996-03-01), None
patent: 09-306544 (1997-11-01), None
patent: 11-214032 (1998-01-01), None
patent: 10-172615 (1998-06-01), None
patent: 11-185804 (1999-07-01), None
patent: 11-238523 (1999-08-01), None
patent: 11-302383 (1999-11-01), None
patent: 11-302384 (1999-11-01), None
patent: 11-306856 (1999-11-01), None
patent: 11-306857 (1999-11-01), None
patent: 2000-058123 (2000-02-01), None
patent: 2000-154254 (2000-06-01), None
patent: 2000-222939 (2000-08-01), None
patent: 2000-277152 (2000-10-01), None
patent: 2001-068115 (2001-03-01), None
patent: 2001-110455 (2001-04-01), None
patent: 2001-185165 (2001-07-01), None
patent: 2001-283907 (2001-10-01), None
patent: 2001-283913 (2001-10-01), None
patent: 2002-063936 (2002-02-01), None
patent: 2002-151150 (2002-05-01), None
patent: 2002 155142 (2002-05-01), None
patent: 2002-298913 (2002-10-01), None
patent: 2002-343440 (2002-11-01), None
patent: 2003-002974 (2003-01-01), None
patent: WO 96/21953 (1996-07-01), None
patent: WO 98/07729 (1998-02-01), None
patent: WO 00/00495 (2000-01-01), None
patent: WO 00/08654 (2000-02-01), None
patent: WO 00/25323 (2000-05-01), None
patent: WO 01/73884 (2001-10-01), None
patent: WO 01/96446 (2001-12-01), None
patent: WO 01/99209 (2001-12-01), None
patent: WO 03/083970 (2003-10-01), None
patent: WO 03/083971 (2003-10-01), None
patent: WO 03/083972 (2003-10-01), None
patent: WO 03/083973 (2003-10-01), None
patent: WO 03/083974 (2003-10-01), None
patent: WO 03/090299 (2003-10-01), None
M. Armand, New Electrode Material, Proceedings of the NATO Sponsored Advanced Study Institute on Fast Ion Transport in Solids, Solid State Batteries and Devices, 1972, Belgirate, Italy.
D. Fenton et al., Complexes of Alkali Metal Ions with Poly(Ethylene Oxide), Polymer, Nov. 1973, 589, 14.
S. Kohama et al., Alcoholysis of Poly(methylhydrogensiloxane), Journal of Applied Polymer Science, 1977, 21, 863-867.
E. Tsuchida et al., Conduction of Lithium Ions in Polyvinylidene Fluoride and its Derivates-I, Electrochimica Acta, 1983, 591-595, 28(5).
L. Hardy et al., Chloride Ion Conductivity in a Plasticized Quaternary Ammonium Polymer, Macromolecules, 1984, 975-977, 17.
P. Blonsky et al., Polyphosphazene Solid Electrolytes, Journal of American Chemical Society, 1984, 6854-6855, 106.
D. Bannister et al., A Water-Soluble Siloxane: Poly(ethylene glycol) Comb Polymer, Journal of Polymer Science: Polymer Letters Edition, 1985, 465-467, 23.
I. Kelly et al., Poly(Ethylene Oxide) Electrolytes for Operation at Near Room Temperature, Journal of Power Sources, 1985, 13-21, 14.
D. Fish et al., Conductivity of Solid Complexes of Lithium Perchlorate with Poly {[w-methoxyhexa(oxyethylene)ethoxy]methylsiloxane}a), Makromol. Chem., Rapid Commun., 1986, 115-120, 7.
P. Hall et al. Ion Conductivity in Polysiloxane Comb Polymers With Ethylene Glycol Teeth, Polymer Communications, 1986, 3 pages, 27.
D.R. MacFarlane et al., Synthesis and Aqueous Solution Phase Behavior of Siloxane-Poly (Alkylene Glycol) Comb Copolymers, Department of Chemistry, Monash University, Clayton, Victoria, Australia,Polymer Preprints,1987, 28, 405-406.
D. Fish et al., Polymer Electrolyte Complexes of CIO4and Comb Polymers of Siloxane with Oligo-oxyethylene Side Chains, British Polymer Journal, 1988, 281-288, 20, 3.
S. Ganapathiappan et al., A New Class of Cation Conductors: Polyphosphazene Sulfonates, Macromolecules, 1988, 2299-2301, 21.
I. Khan et al., Comblike Polysiloxanes with Oligo(oxyethylene) Side Chains, Synthesis and Properties, Macromolecules, 1988, 2684-2689, 21.
R. Spindler et al., Investigations of a Siloxane-Based Polymer Electrolyte Employing13C,29Si,7Li, and23Na Solid State NMR Spectroscopy, Journal of American Chemical Society, 1988, 3036-3046, 110.
R. Spindler et al., Synthesis NMR Characterization, and Electrical Properties of Siloxane-Based Polymer Electrolytes, Macromolecules, 1988, 648-654, 21.
S. Ganapathiappan et al., Synthesis, Characterization and Electrical Response of Phosphazene Polyelectrolytes, Journal of America Chemical Society, 1989, 4091-4095, 111.
M. Ouchi et al., Convenient and Efficient Tosylation

LandOfFree

Say what you really think

Search LandOfFree.com for the USA inventors and patents. Rate them and share your experience with other people.

Rating

Solid polymer electrolyte and method of preparation does not yet have a rating. At this time, there are no reviews or comments for this patent.

If you have personal experience with Solid polymer electrolyte and method of preparation, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Solid polymer electrolyte and method of preparation will most certainly appreciate the feedback.

Rate now

     

Profile ID: LFUS-PAI-O-3856591

  Search
All data on this website is collected from public sources. Our data reflects the most accurate information available at the time of publication.