Organic compounds -- part of the class 532-570 series – Organic compounds – Heterocyclic carbon compounds containing a hetero ring...
Patent
1980-06-02
1982-03-30
Rotman, Alan L.
Organic compounds -- part of the class 532-570 series
Organic compounds
Heterocyclic carbon compounds containing a hetero ring...
564468, 564509, C07D21354, C07C 9703
Patent
active
043225373
ABSTRACT:
Tertiary amines in which at least one group bonded directly to the nitrogen atom is alkyl of 2 to 20 carbon atoms or in which two or more groups bonded directly to the nitrogen atom together are alkylene of 4 to 7 carbon atoms, are oxidized by trihaloacetyl anhydride or trihaloacetyl halide to mono- and di-trihaloacetylated alpha, beta-enamines.
REFERENCES:
Leonard et al. (1957), J. Am. Chem. Soc., 79, 5279.
Damico et al. (1966), J. Org. Chem., 31, 1607.
Jones et al. (1925), J. Am. Chem. Soc., 46, 1343.
Meerwein et al. (1960), Justus Liebigs Ann. Chem., 635, 1.
Volz et al. (1971), Justus Liebigs Ann. Chem., 752, 86.
Horner et al. (1957), Justus Liebigs Ann. Chem., 597, 20.
President and Fellows of Harvard College
Rotman Alan L.
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