Mixed ester retreated propylene polymerization catalyst

Catalyst – solid sorbent – or support therefor: product or process – Catalyst or precursor therefor – Plural component system comprising a - group i to iv metal...

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502121, 502122, 502123, 502124, 502125, 502126, 502127, 526124, 526125, C08F 464

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045268827

ABSTRACT:
A comminuted, supported polymerization catalyst for alpha-olefins comprises (A) an organoaluminum compound and (B) a solid titanium-containing component formed by at least one halogen-containing compound of titanium(IV); (b) at least one electron donor; and (c) at least one hydrocarbon-insoluble magnesium-containing compound; and (2) retreating such comminuted product with (a) at least one halogen-containing compound of titanium(IV); and (b) a mixture containing ethylbenzoate and a substituted alkyl aromatic acid ester in which the substituent group has a negative Hammett constant; and optionally, at least one chlorocarbon and/or at least one haloalkylchlorosilane.

REFERENCES:
patent: 4431570 (1984-02-01), Johnson
patent: 4431571 (1984-02-01), Karayannis
patent: 4431572 (1984-02-01), Karayannis et al.

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