Process for the preparation of glycolaldehyde

Details Process for the preparation of glycolaldehyde Process for the preparation of glycolaldehyde

2007-11-27

2007-11-27

Witherspoon, Sikarl A. (Department: 1621)

Organic compounds -- part of the class 532-570 series

Organic compounds

Oxygen containing

C568S458000

Reexamination Certificate

active

11693542

ABSTRACT:
Disclosed are catalyst solutions for the hydroformylation of formaldehyde comprising one or more fluorophosphite compounds, rhodium and a hydroformylation solvent comprising at least one N,N-disubstituted amide, N-substituted cyclic amide, or a mixture thereof. Also disclosed are hydroformylation processes wherein formaldehyde is contacted with carbon monoxide, hydrogen one or more fluorophosphite compounds, rhodium and a hydroformylation solvent to produce glycolaldehyde. The fluorophosphite-based catalysts provide good reaction rates and high selectivity to glycolaldehyde.

REFERENCES:
patent: 3560539 (1971-02-01), Booth
patent: 3920753 (1975-11-01), Yukawa et al.
patent: 3948965 (1976-04-01), Cawse
patent: 4072720 (1978-02-01), Haag et al.
patent: 4291179 (1981-09-01), Goetz et al.
patent: 4317946 (1982-03-01), Costa
patent: 4321414 (1982-03-01), Costa
patent: 4362820 (1982-12-01), Kaplan
patent: 4390734 (1983-06-01), Knifton
patent: 4405814 (1983-09-01), Carroll et al.
patent: 4450299 (1984-05-01), Oswald et al.
patent: 4477685 (1984-10-01), Chan
patent: 4503260 (1985-03-01), Auvil et al.
patent: 4533756 (1985-08-01), Lin et al.
patent: 4533774 (1985-08-01), Griggs
patent: 4560806 (1985-12-01), Jacobson
patent: 4590298 (1986-05-01), Che
patent: 4608444 (1986-08-01), Jacobson
patent: 4687866 (1987-08-01), Oswald et al.
patent: 4687874 (1987-08-01), Oswald et al.
patent: 4740525 (1988-04-01), Maerkl et al.
patent: 4847423 (1989-07-01), Koprowski et al.
patent: 5059710 (1991-10-01), Abatjoglou et al.
patent: 5756855 (1998-05-01), Abatjoglou et al.
patent: 5840647 (1998-11-01), Puckette et al.
patent: 6130358 (2000-10-01), Tolleson et al.
patent: 6191324 (2001-02-01), Guram et al.
patent: 6515161 (2003-02-01), Kreutzer et al.
patent: 6677268 (2004-01-01), Hillebrand et al.
patent: 6693219 (2004-02-01), Puckette et al.
patent: 6831035 (2004-12-01), Puckette et al.
patent: 6846960 (2005-01-01), Tolleson et al.
patent: 6906225 (2005-06-01), Puckette et al.
patent: 6995292 (2006-02-01), Tolleson et al.
patent: 2004/0059153 (2004-03-01), Magna et al.
patent: 2004/0152928 (2004-08-01), Drent et al.
patent: 0002908 (1979-07-01), None
patent: 0331512 (1989-09-01), None
patent: 57-118527 (1982-07-01), None
patent: 62-209032 (1987-09-01), None
patent: 1310383 (1987-05-01), None
patent: WO 2005-058788 (2005-06-01), None
patent: WO 2005-063668 (2005-07-01), None
Baricelli et al, “Homogeneous Catalysis Reaction of Formaldehyde with Synthesis Gas Using Rhodium Complexes” http://www.scielo.cl/scielo.php?script=sci—arttext&pid=S036616442000000300008&Ing=en&nrm=iso&ting=en (believed to have been downloaded Jul. 14, 2006).
Chan et al, “Rhodium-Catalyzed Hydroformylation of Formaldehyde”, Journal of Molecular Catalysis, 19, (1983) pp. 377-391.
Jacobson, “Formaldehyde Hydroformylation to Glycol Aldehyde Via Rhodium Phosphine-Amine and Phospine-Amide Catalysts”, Journal of Molecular Catalysis, 41 (1987) pp. 163-183.
Marchionna et al, “Hydroformylation of Formaldehyde Catalyzed by Rh4(CO)12In the Presence of Phosphine Ligands and Acids (*)”, Gazzetta Chimica Italiana, 116 (1986) pp. 453-457.
Marchionna, M. “Oxygenates by Homologation of CO Hydrogenation With Metal Complexes” inCatalysis By Metal Complexes,vol. 16 (1994), Edited by G. Braca; Kluwer Academic Publishers (Dordrecht), pp. 191-219.
Co-pending U.S. Appl. No. 11/670,628, filed on Feb. 2, 2007 (D80524).

Affiliated with

Also associated with

Rating

Process for the preparation of glycolaldehyde does not yet have a rating. At this time, there are no reviews or comments for this patent.

If you have personal experience with Process for the preparation of glycolaldehyde, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Process for the preparation of glycolaldehyde will most certainly appreciate the feedback.

Rate now

Comments { 0 }

Profile ID: LFUS-PAI-O-3814297