Raman spectroscopy method, raman spectroscopy system and...

Optics: measuring and testing – By dispersed light spectroscopy – With raman type light scattering

Reexamination Certificate

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Reexamination Certificate

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11029016

ABSTRACT:
In a Raman spectroscopy, the surface of metal film which is formed on a dielectric substrate in thickness of 50 to 200 nm and is characterized in that a plurality of fine holes satisfying the conditions defined by the following formulae are formed is caused to adsorb the material to be analyzed, light is projected onto the surface and the scattering light scattered by the surface is separated to obtain a spectrum of the scattering light,λ=a⁢⁢(ɛ⁢⁢1·ɛ2ɛ1+ɛ2)12in-line-formulae description="In-line Formulae" end="lead"?d<λin-line-formulae description="In-line Formulae" end="tail"?wherein λ represents the wavelength of the projected light, a represents the cycle of the fine holes, d represents the diameter of the fine holes, ε 1 represents the dielectric constant of the metal film and ε 2 represents the dielectric constant of the medium around the surface of the metal film.

REFERENCES:
patent: 2003-268592 (2003-09-01), None
patent: 2004-232027 (2004-08-01), None
patent: WO 01/06257 (2001-01-01), None
Brolo et al., Nanohole-Enhanced Raman Scattering, NANO Letters, vol. 4, No. 10, 2004, Published on Web Sep. 11, 2004.
“Brilliant Optical Properties of Nanometric Noble Metal Spheres, Rods, and Aperture Arrays”, Peter C. Andersen, et al., Applied Spectroscopy, vol. 56, No. 5, pp. 124A-135A, May 2002.
Haynes C L et al: “Nanosphere lithography: synthesis and application of nanoparticles with inherently anisotropic structures and surface chemistry”, Anisotropic Nanoparticles—Synthesis, Characterization and applications. Symposium (Materials Research Society Symposium Proceedings vol. 635) Mater. Res Soc Warrendale, PA, USA, 'Online! 2001, pp. C6.3. 1-6, XP002324693.
Mulvaney S P et al: “Three-layer substrates for surface-enhanced Raman scattering: preparation and preliminary evaluation” Journal of Raman Spectroscopy Wiley UK 'Online!, vol. 34, No. 2, 2003, pp. 163-171, XP002324694.

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