Concentrating column and sample processing device useful for...

Measuring and testing – Liquid analysis or analysis of the suspension of solids in a... – Content or effect of a constituent of a liquid mixture

Reexamination Certificate

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C210S692000, C095S088000

Reexamination Certificate

active

11196040

ABSTRACT:
A concentrating column useful for elemental analysis of trace metals consists mainly of column body, filtration membranes6fixed at the fluid inlet end and the outlet end of the column body, and column packing8packed inside the column body, wherein column packing8is prepared from the swollen and cleaned macroporous adsorbent resin of high, medium or non-polarity treated with a mixture of 3 mol/L NH4OH-1 mol/L HAC-3.0˜6.0×10−4mol/L pyridin-(2-azo-4-)resorcin or a mixture of 0.5 mol/L Na2HPO4-1.0˜2.0×10−4mol/L pyridin-(2-azo-4-)resorcin by dynamic on-column treatment or static immersion treatment. Two types of sample processing devices useful for elemental analysis of trace metals are provided with concentrating column employing the above-mentioned column packing. The concentrating column of the present invention simplifies the sample processing flow and the structure of sample processing device, saves chemical reagent, increases sample processing rate, and particularly prevents the toxic methanol from doing harm to the operator's health.

REFERENCES:
patent: 4081401 (1978-03-01), Takegami et al.
patent: 4081403 (1978-03-01), Takegami et al.
patent: 4392963 (1983-07-01), Perl et al.
Smirnov, I. P. and Nesterenko, P.N. “Use of High-Efficiency Liquid-Chromatography in Determining the Metal Content of Waste-Water”, Fibre Chemistry, vol. 24, Sep. 1993, pp. 422-424.
Pauli, B. and Jones, P. “A Comparative Study of the metal Selective Properties of Chelating dye Impregnated Resins for the Ion Chromatographic Separation of Trace Metals.” Chromatographia, vol. 42, May 1996, pp. 528-538.

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