Preparation of 1,3-diamino-2,2-dialkylpropanes

Organic compounds -- part of the class 532-570 series – Organic compounds – Amino nitrogen containing

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564479, C07C 8506

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046224289

ABSTRACT:
1,3-Diamino-2,2-dialkylpropanes whose alkyl substituents are each of 1 to 4 carbon atoms are prepared by reacting the corresponding 2,2-dialkylpropane-1,3-diols with ammonia in the presence of hydrogen under superatmospheric pressure by a process in which the reaction is carried out in solution and in the presence of a cobalt-containing catalyst.

REFERENCES:
patent: 2166152 (1939-07-01), Howk
patent: 3137730 (1964-06-01), Fitz-William
patent: 4014933 (1977-03-01), Boettger et al.
patent: 4078003 (1978-03-01), Feichtinger et al.
J. Am. Chem. Soc. 71, (1949), 3249.
Ullmanns Encyklopadie der Technischen Chemie, 4th ed., vol. 13, pp. 558 et seq.

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