Conversion of methanol to hydrocarbons

Chemistry of hydrocarbon compounds – Unsaturated compound synthesis – From nonhydrocarbon feed

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585733, 502325, C07C 100

Patent

active

045131619

ABSTRACT:
A process wherein methanol is contacted, in the presence of hydrogen, over a ruthenium-titania catalyst to produce, at reaction conditions, an admixture of C.sub.10 + linear paraffin and olefins, which can be further refined and upgraded to high quality middle distillate fuels, and other valuable products such as mogas, diesel fuel, jet fuel, lubes, and specialty solvents, especially premium middle distillate fuels of carbon number ranging from about C.sub.10 to C.sub.20.

REFERENCES:
patent: 4088671 (1978-05-01), Kobylinski
patent: 4338089 (1982-07-01), Schaper et al.
patent: 4385193 (1983-05-01), Bijwaard et al.
92:129385h; The Synthesis of Solid Hydrocarbons From Methanol; Shima, Kensuke, Morita, Tauyoshi, (Miyazaki Univ., Miyazaki, Japan); Nouveau Journal DeChime, vol. 6, No. 10--1982, p. 459.
Fischer-Tropsch Synthesis of Hydrocarbons Over Ruthenium Supported on Transition Metal Oxides; Kikuchi, Nomura, Matsumoto and Morita, (Waseda University, Tokyo 160); Pan-Pacific Synfuels Conference, vol. I, Nov. 17-19, 1982 Tokyo, pp. 1-10.
Fischer-Tropsch Synthesis Over Titania-Supported Ruthenium Catalysts; Kikuchi, Matsumoto, Takahashi, Machino and Morita, (Waseda University, 3-4-1 Okubo, Shinjuku, Tokyo, Japan); Printed in The Netherlands; Applied Catalysis, 10 (1984), pp. 251-260.
IS-T-1006; Hydrogenation of Carbon Monoxide Over Ruthenium-rhenium on Alumina Catalysts; D. E. Whitmoyer (M.S. Thesis submitted to Iowa State University); Prepared for the U.S. Department of Energy Under Contract No. W-7405-eng-82; Jul. 1982.

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