Production of primary and secondary amines by reaction of ammoni

Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal

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252431C, 252431N, 252431P, 260583H, C07C 8518

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active

041209010

ABSTRACT:
Short chain, unsaturated primary and secondary amines are prepared by reaction of ammonia and conjugated dienes in a primary or secondary aliphatic alcohol solvent medium and in the presence of a catalyst system comprising a palladium compound co-catalyzed with a phosphine ligand containing 2 to 4 phosphorus atoms.

REFERENCES:
Takahashi et al., "Bull. Chem. Soc. Jap.", vol. 45, pp. 1183-1191 (1972).

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