Lithiumaluminium hydride compounds

Details Lithiumaluminium hydride compounds Lithiumaluminium hydride compounds

1979-10-05

1981-08-18

Sneed, H. M. S.

Chemistry of carbon compounds

Miscellaneous organic carbon compounds

C-metal

C07F 506

Patent

active

042845815

ABSTRACT:
Lithium 1,1'-binaphthyl-2,2'-dioxyaluminium hydride compounds of the general formula: ##STR1## wherein R.sup.1 represents a hydrogen atom, or a methyl or ethyl group, and R.sup.2 represents a straight- or branched-chain alkyl group containing from 1 to 12 carbon atoms unsubstituted or substituted by at least one fluorine atom, hydroxy group, or straight- or branched-chain alkoxy group containing from 1 to 4 carbon atoms, or represents a phenyl group unsubstituted or substituted by at least one straight- or branched-chain alkyl group containing from 1 to 4 carbon atoms are useful as reducing agents.

REFERENCES:
patent: 2844551 (1958-07-01), Orthner et al.
patent: 3060216 (1962-10-01), Hamprecht et al.
patent: 3147272 (1964-09-01), Brown
patent: 3652622 (1972-03-01), Vit et al.
patent: 3686249 (1972-08-01), Hartmann
patent: 3787450 (1974-01-01), Casensky et al.
Chemical Abstracts, vol. 93, 149842d (1980), (re: Tennen Yuki Kagobutsu Toronkai Koen Yoshishu, 22nd, publ. Sep. 20, 1979).
Tetrahedron 32, 939-944, (1976).
JACS 101, 3129-3131, (1979).

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