Method for producing humic acid salts

Drug – bio-affecting and body treating compositions – Plant material or plant extract of undetermined constitution...

Reexamination Certificate

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C507S108000, C507S107000, C507S106000

Reexamination Certificate

active

10498776

ABSTRACT:
Humic acid salts are produced, with a high output of useful products, by a liquid-phase oxidation of the mixture of an alkaline agent with a lignin-containing plant raw material having the total content of dry substances of 12–20 %, said oxidation being carried out in two stages. In a first stage, pre-oxidation is carried out at a temperature of 50–190 DEG C. and a pressure of 0.5–3 MPa associated with simultaneous treatment with an oxygen-containing gas until a pH of 10.5–12 is reached. The second stage, i.e. oxidation is carried out in the similar conditions at a temperature of 170–200 DEG C. until a pH of 8.5–10 is reached. The by-product of cellulose production by a sulphite process, i.e. concentrated solutions of lignosulphonate or lignin is used as a lignin-containing plant raw material, said lignin being a by-product of hydrolysis production being continuously oxidised by air oxygen in two stages. In order to additionally activate the mixture of the raw material with alkali, operating in cavitation mode, a circulation pump provided with an ejector for stream ejection of air is used. In order to reduce the pre-oxidation time, the first stage can be carried out using peroxide, or by supplying the raw material and alkali directly to a pipeline prior to an ejector and the mixture thereof with an oxidising agent.

REFERENCES:
patent: 4459149 (1984-07-01), Moran et al.
patent: 5026416 (1991-06-01), Alexander
patent: 5302180 (1994-04-01), Hjersted
patent: 5688999 (1997-11-01), Lebo, Jr. et al.
patent: 0 101 784 (1984-03-01), None
patent: 2108811 (1998-04-01), None
patent: 2125039 (1999-01-01), None
English translation of RU 2 108 811.

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