Olefin polymerization catalyst system

Catalyst – solid sorbent – or support therefor: product or process – Catalyst or precursor therefor – Plural component system comprising a - group i to iv metal...

Reexamination Certificate

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C502S103000, C502S115000, C502S123000, C526S348000, C526S124200, C526S124300, C526S128000, C526S141000

Reexamination Certificate

active

07122497

ABSTRACT:
A catalyst system useful for polymerizing olefins is disclosed. The catalyst system comprises a cocatalyst and a supported transition metal prepared from a halogen-containing Group 4–6 transition metal compound and an organoaluminum-siloxane containing mixture. The latter mixture, which is prepared from an organoaluminum compound and an organomagnesium-siloxane reaction product, incorporates a chelating ligand. The invention includes a method for making the catalyst system and a process for polymerizing olefins using the catalyst system. The process is convenient and avoids expensive catalyst components used in known olefin polymerization processes.

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J. Severn et al.,Polym Int 54(2005) 837.
Y. Nakayama et al.,Science and Technology In Catalysis(2002) 517.

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