Organic compounds -- part of the class 532-570 series – Organic compounds – Heterocyclic carbon compounds containing a hetero ring...
Reexamination Certificate
2006-06-27
2006-06-27
Saeed, Kamal A. (Department: 1626)
Organic compounds -- part of the class 532-570 series
Organic compounds
Heterocyclic carbon compounds containing a hetero ring...
C546S315000
Reexamination Certificate
active
07067673
ABSTRACT:
A process for the production of acetylopyridines of the formula (1):by reacting a pyridinecarboxylic ester of the formula (II):wherein R1is C1-6-alkyl, with acetic acid in the gas phase in the presence of a catalyst. The active material of the catalyst is titanium dioxide and at least one alkali or alkaline earth metal oxide, and it is supported on an alumina-silica support having an apparent porosity of at least 50 percent. The process has the advantage of producing only small amounts of by-products (e.g, pyidine).
REFERENCES:
patent: 3979400 (1976-09-01), Rieger et al.
patent: 4950763 (1990-08-01), Schommer et al.
patent: 0352674 (1990-01-01), None
patent: 1249079 (1971-10-01), None
patent: 98/50374 (1998-11-01), None
International Search Report for applicants corresponding International patent application.
Girardon, Marc, et al., Journal of Organic Chemistry, vol. 63, No. 26, (1998), pp. 10063-10068.
Houben-Weyl, vol. VII/2a, pp. 632-633.
Fisher Christen & Sabol
Grazier Nyeemah
Lonza AG
Saeed Kamal A.
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