Copolymers useful as cement additives and a process for their pr

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – From heterocyclic reactant containing as ring atoms oxygen,...

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528405, 528409, 528417, 528419, 528421, C08G 5900

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active

060342080

ABSTRACT:
Unique, well defined macromonomers containing hydroxyl-functionality, unsaturation-functionality, and polyoxyalkylene segments are prepared by oxyalkylating an unsaturated initiator molecule having at least one oxyalkylatable hydrogen in the presence of an effective amount of a double metal cyanide complex catalyst, optionally, when necessary, in the presence of a free radical polymerization inhibitor. The resulting unsaturated macromonomers are eminently suitable for such uses as copolymerization with ethylenically unsaturated monomers containing carboxylic acid-based groups such as acrylic acid to form effective superplasticizers and water reducers for cement and concrete applications.

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