Organic compounds -- part of the class 532-570 series – Organic compounds – Nitrogen attached directly or indirectly to the purine ring...
Reexamination Certificate
2006-10-03
2006-10-03
McKenzie, Thomas C. (Department: 1624)
Organic compounds -- part of the class 532-570 series
Organic compounds
Nitrogen attached directly or indirectly to the purine ring...
Reexamination Certificate
active
07115742
ABSTRACT:
A process for the preparation of triethylenediamine (TEDA) by reaction of ethylenediamine (EDA) in the presence of a zeolite catalyst, wherein the zeolite catalyst contains one or more metals M in oxidation states II, III or IV as oxides. The desired molar ratio of SiO2to metal oxide of the zeolite catalyst depends on the oxidation state of the metal M as specified herein. The reaction temperature is from 250 to 500° C. TEDA is an important basic chemical and is used, among other things, in the preparation of pharmaceuticals and plastics, in particular as a catalyst in the preparation of polyurethanes.
REFERENCES:
patent: 2937176 (1960-05-01), Herrick
patent: 3285920 (1966-11-01), Muhlbauer et al.
patent: 3702886 (1972-11-01), Argauer et al.
patent: 3956329 (1976-05-01), Murakami et al.
patent: 4289881 (1981-09-01), Imre et al.
patent: 4804758 (1989-02-01), Hoelderich et al.
patent: 4966969 (1990-10-01), Sato et al.
patent: 5041548 (1991-08-01), Sato et al.
patent: 5053374 (1991-10-01), Absil et al.
patent: 5280120 (1994-01-01), King
patent: 5731449 (1998-03-01), Li et al.
patent: 5741906 (1998-04-01), Santieteban et al.
patent: 5756741 (1998-05-01), Armor et al.
patent: 6084096 (2000-07-01), Li et al.
patent: 6350874 (2002-02-01), Ogawa
patent: 6380119 (2002-04-01), Grosch et al.
patent: 206 896 (1984-02-01), None
patent: 158 319 (1985-10-01), None
patent: 312 734 (1989-04-01), None
patent: 313 753 (1989-05-01), None
patent: 349 859 (1990-01-01), None
patent: 382 055 (1990-08-01), None
patent: 423 526 (1991-04-01), None
patent: 831 096 (1998-03-01), None
patent: 1 041 073 (2000-10-01), None
patent: 2071475 (1997-01-01), None
patent: 2114849 (1998-07-01), None
patent: WO 89/05810 (1989-06-01), None
patent: 98/55228 (1998-10-01), None
patent: WO 01/02404 (2001-01-01), None
Reichle, W.T., J. Catalysis, 144, 1993, 556-568.
Ullmann's Enc. of Ind. Chemistry, 5th Ed., vol. A28, pp. 487-490, “Zeolites” (VCH Publishers, 1996).
Klockemann et al., “Method for the production of triethylene diamine making use of ethylene diamine”; U.S. Appl. No. 09/609,740.
Reichle, “Reactions of Aliphatic α,ω-diamines in H+-Pentasils”Journal of Catalysts, vol. 144, 1993, pp. 556-568.
Weitkamp et al.,Catalysis and Zeolites, Fundamentals and Applications, Chapter 3, pp. 81-197, 1999.
XP-002253039, Chem.Abst. 134:268039.
Frauenkron Matthias
Stein Bernd
BASF - Aktiengesellschaft
McKenzie Thomas C.
Novak Druce & Quigg
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