Aqueous film-forming mixtures and conformable films and...

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – At least one aryl ring which is part of a fused or bridged...

Reexamination Certificate

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Details

C525S124000, C428S343000

Reexamination Certificate

active

06989418

ABSTRACT:
This invention relates to an aqueous film-forming mixture which does not contain a vinyl halide and which can be utilized to prepare conformable films which are useful in various applications such as adhesive tapes, labels and decorative sheets. The aqueous film-forming mixtures generally comprise, based on the weight of the solids in the aqueous mixture, (A) from about 50% to about 80% by weight of an acrylic-urethane copolymer which forms a film having an elongation at break of at least about 300%, and (B) from about 5% to about 25% by weight of an acrylic polymer or copolymer having a Tgof less than about 55° C., wherein the acrylic polymer or copolymer (B) is different from the acrylic-urethane copolymer (A). The aqueous mixtures also may contain up to about 40% by weight of a pigment. These aqueous film-forming mixtures are useful in preparing conformable films and other articles such as adhesive articles which comprise an adhesive layer and a layer of the conformable film of this invention which is adhered to the adhesive layer. The conformable films of the present invention may be printed with various graphics, and the films are die-cuttable.

REFERENCES:
patent: 5629374 (1997-05-01), Budde et al.
patent: 5643669 (1997-07-01), Tsuei
patent: 5688573 (1997-11-01), Goeb et al.
patent: 5783303 (1998-07-01), Tsuei
patent: 6001947 (1999-12-01), Brunnemann et al.
patent: 6284037 (2001-09-01), Sapper
patent: 424 705 (1990-10-01), None
patent: 98/45347 (1998-10-01), None
patent: 99/16805 (1999-04-01), None
NeoPac R-9000; Bulletin R-9000; Aug., 2000.
NeoPac R R-9699; Bulletin R-9699; Dec., 2001.
Acronal Optive® 110; Architectural Coatings Raw Materials; Straight Acrylic Resin for Semi-Gloss Paints at 150 g/l VOC with Superior Block Resistance; BASF; Revised Jul. 16, 2001.
Acronal® 296 D; Architectural Coatings Raw Materials; Styrene Acrylic Latex for General Purpose Interior and Exterior Coatings; BASF; Revised Sep. 10, 2001.
Acronal Optive® 310; Architectural Coatings Raw Materials; Styrene Acrylic Latex Polymer for High Gloss Wall and Trim Paints with Stain Resistance at 150 g/l VOC; BASF; Revised Oct. 29, 2001.
Acronal Optive® 320; Architectural Coatings Raw Materials; Straight Acrylic Resin for High Gloss Wall & trim Paints with Excellent Lanolin Resistance; BASF; Revised Jun. 2002.
Kronos 4102 Data Sheet.

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