Process for manufacture of maleic anhydride catalysts

Catalyst – solid sorbent – or support therefor: product or process – Catalyst or precursor therefor – Phosphorus or compound containing same

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502162, 502211, 549257, 549259, 549260, 549262, B01J 27198, B01J 3728, C07D30734

Patent

active

050195450

ABSTRACT:
Novel maleic anhydride catalysts comprising phosphorus-vanadium oxides and phosphorus-vanadium-co-metal oxides wherein said catalysts do not expand under reaction conditions for the manufacture of maleic anhydride and a process for preparing these catalysts are disclosed. The process comprises reacting a vanadium compound with a phosphoryl halide in the presence of water in an atmosphere comprising at least about 0.1% oxygen wherein the molar ratio of water to phosphorus from the phosphoryl halide is in the range of about 2.25:1 to about 3.75:1.

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