Process for production of dimers or aromatic monohydroxyl...

Organic compounds -- part of the class 532-570 series – Organic compounds – Oxygen containing

Reexamination Certificate

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C552S291000, C552S292000, C552S304000, C560S045000, C560S056000, C564S153000, C568S730000

Reexamination Certificate

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06891072

ABSTRACT:
The present invention provides a method for preparing dimer of a monohydroxy aromatic compound. In the method of the present invention, oxidative coupling reaction of a monohydroxy aromatic compound represented by formula [I]:in-line-formulae description="In-line Formulae" end="lead"?Ar—OH  [I]in-line-formulae description="In-line Formulae" end="tail"?wherein Ar represents an optionally substituted aromatic groupis carried out in a nitrogen containing polar solvent in the presence of a copper salt. By the method of the instant invention, dimer of the monohydroxy aromatic compound can be obtained in high yield.

REFERENCES:
patent: 3278610 (1966-10-01), Butte, Jr.
patent: 3631208 (1971-12-01), Hay
patent: 4085124 (1978-04-01), Rutledge
patent: 4139544 (1979-02-01), Rutledge
patent: 20040063963 (2004-04-01), Ueno et al.
patent: 62-77341 (1987-04-01), None
patent: 6-145086 (1994-05-01), None
patent: 8-20552 (1996-01-01), None
patent: 8-245459 (1996-09-01), None
patent: 10-204015 (1998-08-01), None

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