Ion liquids derived from Lewis acid based on titanium,...

Catalyst – solid sorbent – or support therefor: product or process – Catalyst or precursor therefor – Organic compound containing

Reexamination Certificate

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C502S164000, C502S167000, C502S168000, C502S169000, C570S166000, C570S167000, C570S168000, C570S169000

Reexamination Certificate

active

06881698

ABSTRACT:
The ionic liquids according to the invention result from the reaction of a halogenated or oxyhalogenated Lewis acid based on titanium, niobium, tantalum, tin or antimony with an organic salt of formula X+A−in which A−is a halide anion and X+a quaternary ammonium, quaternary phosphonium or ternary sulphonium cation. These liquids can be used in particular in the liquid-phase fluorination using HF of saturated or unsaturated compounds having C—Cl groups.

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J. Robinson and R.A. Osteryoung, “An Electrochemical and Spectroscopic Study of Some Aromatic Hydrocarbons in the Room Temperature Molten Salt System Aluminum Chloride-n-Butylpyridinium Chloride”, Journal of the American Chemical Society, vol. 101:2, pp. 323-327, dated Jan. 17, 1979.
John S. Wilkes, et al., “Dialkylimidazolium Chloroaluminate Melts: A New Class of Room-Temperature Ionic Liquids for Electrochemistry, Spectroscopy, and Synthesis”, Inorg. Chem. vol. 21, No. 3, pp. 1263-1264, dated 1982.

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