Sterically regulated methacrylic polymer and process for...

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Polymers from only ethylenic monomers or processes of...

Reexamination Certificate

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C526S126000, C526S170000, C526S259000, C526S326000

Reexamination Certificate

active

06864338

ABSTRACT:
This invention provides a high-molecular-weight, sterically regulated methacrylic polymer having high stereoregularity, a narrow distribution of molecular weights, and a high molecular weight, comprising methacrylates as units containing triphenyl amino groups etc. in side chains. The sterically regulated methacrylic polymer comprises 50 to 100 mol-% unit based on methacrylate (1) having a tertiary amino group bound to at least two aromatic rings in a side chain, wherein the number-average molecular weight (Mn) is 5000 to 2000000, the poly dispersity coefficient (Mw/Mn) is 1 to 1.5, and the syndiotacticity of the methacrylic polymer is 70% or more in 2-units expression (%rr).

REFERENCES:
patent: 5116911 (1992-05-01), Leyrer et al.
patent: 62-70408 (1987-03-01), None
patent: 62-070408 (1987-03-01), None
patent: 3-263412 (1991-11-01), None
patent: 10-265517 (1998-10-01), None
patent: 10-333195 (1998-12-01), None
Keyanpour-Rad et al. Macromolecules (1978), 11(6), 1114-8.*
Vyprachticky et al. Macromol et al. Chem. Phys., (1999), 200(3), 580-586.*
Cho et al. Polymer Preprints (2000), 41(2), 1223-1224.*
John C. Jansen, et al., Synthesis and characterization of novel side-chain liquid polycarbonates, 4. Synthesis of side-chain liquid crystalline polycarbonates with mesogenic groups having tails of different lengths, Macromolecular Chemistry and Physics, vol. 200, Issue 6 pp. 1407-1420, Nov. 20, 1998.
George J. Jiang, et al., Polymerization of methyl methacrylate using a metallocene catalyst system, Journal of Polymer Science Part A: Polymer Chemistry, vol. 38, Issue 7, pp. 1184-1194, Jan. 5, 2000.
O. Hampel, et al., New Derivatives of Quinoxaline—Syntheses, Complex Formalation and their Application as Controlling Ligands for Zinc Catalyzed Epoxide-CO2-Copolymerization, 2002 Verlag der Zeitschrift für Naturforschung, Tübingen, pp. 946-956.
P.L. Watson, et al., Homogeneous Lanthanide Complexes as Polymerization and Oligomerization Catalysts: Mechanistic Studies, 1983 American Chemical Society, pp. 459-479.
William J. Evans, et al., Organolanthanide Hydride Chemistry. 3. Reactivity of Low-Valent Samarium with Unsaturated Hydrocarbons Leading to a Structurally Characterized Samarium Hydride Complex, American Chemical Society, 1983, 105, 1401-1403.
Kazuo Soga, et al., Stereospecific Polymerization of Methyl Methacrylate Initiated by Dimethylzirconocene/B(C6F5)3(or Ph3CB(C6F5)4)/Zn(C2H5)2, American Chemical Society, 1994, 27, 7938-7940.
Colin Eaborn, et al., A Monomeric Solvent-Free Bent Lanthanide Dialkyl and a Lanthanide Analogue of a Grignard Reagent. Crystal Structures of Yb{C(SiMe3}wand [Yb{C(SiMe3}I OEt2]2, American Chemical Society, 1994, 116, 12071-12072.
Gerald Jeske, et al., Highly Reactive Organolanthanides. Systematic Routes to and Olefin Chemistry of Early and Late Bis(pentamethylcylopentadieny/) 4f Hydrocarbyl and Hydride Complexes, American Chemical Society, 1985, 107, 8091-8103.

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