Process for production of biphenyltetracarboxylic acid...

Organic compounds -- part of the class 532-570 series – Organic compounds – Carboxylic acid esters

Reexamination Certificate

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C560S096000, C544S225000, C546S002000, C585S422000

Reexamination Certificate

active

06914154

ABSTRACT:
A production process, especially a continuous production process, for a biphenyltetracarboxylic acid tetraester characterized by carrying out, in parallel, a step of preliminarily mixing a phthalic acid diester and a palladium compound-containing catalyst to prepare a starting mixture, a step of continuously or intermittently supplying the starting mixture to a reactor, a step of conducting oxidative dimerization reaction of the phthalic acid diester in a temperature range of from 140° C. and lower than 250° C. while supplying molecular oxygen to the reactor to form a reaction mixture in the reactor, and a step of continuously or intermittently removing a portion of the reaction mixture from the reactor. Preferably, the palladium compound-containing catalyst in the starting mixture is dissolved in the phthalic acid diester, the palladium compound-containing catalyst comprises a palladium compound, a bidentate ligand and a copper compound, the reactor consists of a plurality of serially connected reactors and a carboxylic acid is also continuously or intermittently supplied to the reactor.

REFERENCES:
patent: 4581469 (1986-04-01), Itatani et al.
patent: 60-51150 (1985-03-01), None
patent: 61-106541 (1986-05-01), None
patent: 64-48 (1989-01-01), None
patent: 64-56649 (1989-03-01), None
patent: 2000-186063 (2000-07-01), None

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