Production of alkyl (alkylthio) carboxylates

Details Production of alkyl (alkylthio) carboxylates Production of alkyl (alkylthio) carboxylates

1977-10-28

1980-01-22

Garner, Vivian

Organic compounds -- part of the class 532-570 series

Organic compounds

Carboxylic acid esters

260399, 560 10, 560 15, C07C14800, C07C14920

Patent

active

041851552

ABSTRACT:
A process for an acid catalyzed esterification of a mercapto-carboxylic acid followed by an in situ S-alkylation of the mercapto-ester by slow addition of aqueous base to a mixture of said ester and an alkylating agent.

REFERENCES:
patent: 2601063 (1952-06-01), Smith et al.
patent: 2990424 (1961-06-01), Guinot et al.
patent: 3758549 (1973-09-01), Dexter et al.
Carpenter et al., J. Chem. Soc., 2016, (1970).
Mooradian et al., J. Am. Chem. Soc., 71, 3372, (1949).
Chem. Abstracts, 7301c, (1957).

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