Process for making hydroxy-terminated aromatic oligomeric phosph

Organic compounds -- part of the class 532-570 series – Organic compounds – Phosphorus esters

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C07F 9145

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active

055084621

ABSTRACT:
The present invention is a process for forming hydroxy-terminated aromatic oligomeric phosphates by the initial reaction of a monoaryl dihalophosphate, such as monophenyl dichlorophosphate, with an aromatic diol, such as resorcinol, to form a halo-terminated aromatic oligomeric phosphate and the subsequent reaction of that halo-terminated phosphate with aromatic diol to form the hydroxy-terminated aromatic oligomeric phosphate. The initial and subsequent reactions preferably employ a Lewis acid catalyst, such as magnesium dichloride.

REFERENCES:
patent: 2682521 (1954-06-01), Coover, Jr.
patent: 2952666 (1960-09-01), Coover, Jr. et al.
patent: 3965220 (1976-06-01), Schumacher
patent: 4463130 (1984-07-01), Serini et al.
patent: 4510101 (1985-04-01), Pawloski et al.
patent: 5393621 (1995-02-01), Chaloner-Gill
Chemical Abstracts, vol. 92, No. 24140; Petreus et al. Ro-64218 (31 Mar. 1978).

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