Thermoelectric unicouple used for power generation

Details Thermoelectric unicouple used for power generation Thermoelectric unicouple used for power generation

2002-05-01

2004-01-06

Ryan, Patrick (Department: 1745)

Batteries: thermoelectric and photoelectric

Thermoelectric

Processes

C136S236100, C136S239000, C136S241000

Reexamination Certificate

active

06673996

ABSTRACT:

BACKGROUND OF THE INVENTION
1. Field of the Invention
A high-efficiency thermoelectric unicouple is used for power generation.
2. Description of the Related Art
No single thermoelectric material has been suitable for use over a very wide range of temperatures, e.g. such as between 300 and 1000 degrees Kelvin. Prior art techniques have used different thermoelectric materials and have been limited to relatively narrow temperature ranges. Each material is used in the range where it possesses the optimum performance.
Thermoelectric generator devices can be used to create electrical energy based on temperature differentials. Many different thermoelectric materials and forms are known. It is often desirable to operate a thermoelectric generator over a large temperature gradient to increase higher thermal to electrical efficiency. For example, thermoelectric generators may be used in applications such as deep space missions, where other generators might have difficulties in operation.
No single thermoelectric material has been suitable for use over a very wide range of temperatures, e.g. such as between 300 and 1000 degrees Kelvin. Prior art techniques have used different thermoelectric materials and have been limited to relatively narrow temperature ranges. Each material is used in the range wherein possesses the optimum performance.
Generators are known which include a multistage thermoelectric generator where each state operates over a fixed temperature difference and is electrically insulated but thermally in contact with the other stages. An alternative approach uses segmented unicouples/generators, having p and n type materials, formed of different material segments but joined in series.
BRIEF SUMMARY OF THE INVENTION
The present system describes a thermoelectric generator or unicouple formed of segmented thermoelectric parts. The unicouple may be formed of special thermoelectric materials including skutterudites, Specific materials may include Zn
4
Sb
3
materials, CeFe
4
Sb
12
based alloys, both of which are p type materials. N type materials may also be used including CoSb
3
based alloys. Special techniques may be used to reduce the contact resistance of connection to the thermoelectric legs.


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