Innovative method to build a high precision analog capacitor...

Semiconductor device manufacturing: process – Chemical etching – Combined with the removal of material by nonchemical means

Reexamination Certificate

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C438S694000, C438S699000, C438S702000, C438S706000

Reexamination Certificate

active

06706635

ABSTRACT:

TECHNICAL FIELD OF INVENTION
The present invention relates generally to integrated circuits, and more particularly, to a method of forming a high precision analog capacitor for use in an integrated circuit.
BACKGROUND OF THE INVENTION
The manufacturing of semiconductor devices is a combination of the creation of a variety of components that collectively perform functions of data manipulation (logic functions) and of data retention (storage functions). The vast majority of these functions operate in a digital or on/off mode, and as such, recognizes “zero” and “one” conditions within the operational levels of the circuits. There are, in addition, applications that make use of analog levels of voltage, for example, wherein the voltage may have a spectrum of values between a high limit and a low limit. Furthermore, applications exist where both digital and analog methods of signal processing reside in the same semiconductor device.
A mixture of functions and processing capabilities brings with it a mixture of components that can co-exist within one semiconductor device. Where the vast majority of device components is made up of transistors and a variety of switching components that address logic processing functions, it is not uncommon to also see resistors and capacitors that form part of a semiconductor device. For instance, it is known that capacitors form a basic component of many analog circuits that are used for analog applications such as analog-to-digital and digital-to-analog data conversion. Besides A/D conversion, capacitors perform a variety of critical tasks required to interface digital data with the external world, such as amplification, pre-filtering demodulation and signal conditioning. It is also well known in the art that capacitors are widely applied in digital applications such as the storage node for Dynamic Random Access Memory (DRAM) circuits. In general, an analog capacitor stores information in various states, whereas a digital capacitor stores information in two states, namely, low and high. Typical analog applications involve analog-to-digital or digital-to-analog data conversion. Beside data conversion
In reference to the manufacture of analog capacitors,
FIG. 1A
illustrates a cross-sectional view
100
of a conventional analog capacitor
105
, and
FIG. 1B
illustrates a conventional method
150
of fabrication of said capacitor. One of the first processing steps that is required in forming the capacitor
105
on the surface of a semiconductor substrate
110
is to electrically isolate the active regions (the regions where transistor devices will be created) on the surface of the substrate. Act
160
of
FIG. 1B
isolates the device
105
from other devices (not shown) on the semiconductor substrate
110
by forming a field oxide (F
OX
)
115
. One conventional approach in the semiconductor industry for forming the F
OX
115
is by the Local Oxidation of Silicon (LOCOS) method. LOCOS typically uses a patterned silicon nitride (Si
3
N
4
) layer (not shown) as an oxidation barrier mask, wherein the underlying silicon substrate
110
is selectively oxidized. One disadvantage of utilizing LOCOS is that a non-planar surface of the semiconductor substrate results. Another method of forming the field oxide (F
OX
) is to utilize Shallow Trench Isolation (STI) (not shown). One method of utilizing STI is to first etch trenches (not shown) having essentially vertical sidewalls in the silicon substrate. The trenches are typically then filled with a Chemical Vapor Deposition (CVD) of silicon oxide (SiO
2
) and the silicon oxide is then plasma etched or planarized using CMP to form an STI region which is significantly planar.
Following the formation of the F
OX
115
, a polysilicon layer
120
is formed over the F
OX
115
in act
162
of
FIG. 1B
to define a bottom plate
121
of a capacitor
105
. A silicide layer
125
is subsequently formed over the polysilicon layer
120
in act
164
to form a conductive etch stop over the polysilicon layer. The formation of the polysilicon layer
120
typically forms a vertical step
127
on the surface of the substrate
110
. Unfortunately, this vertical step
127
results in deleterious effects when forming the capacitor
105
in the prior art, as will be described hereafter.
Subsequent to forming the polysilicon layer
120
and silicide layer
125
, an oxide layer
130
is blanket deposited over the substrate in act
166
of
FIG. 1B
, typically by Low Pressure Chemical Vapor Deposition (LPCVD) to form a dielectric layer for the capacitor
105
. A titanium nitride (TiN) layer
135
is then deposited over the substrate
110
in act
168
of
FIG. 1B. A
titanium nitride (TiN) hard mask layer
137
which is selective with respect to the underlying TiN layer
135
is furthermore formed over the TiN layer
135
in act
170
. A capacitor masking pattern (not shown) is formed in act
172
, whereby a subsequent hard mask etch and TiN etch are performed in act
174
, thereby removing portions of the TiN hard mask layer
137
and TiN layer
135
to define a top plate
140
of the capacitor
105
.
Following the TiN etch of act
174
, an Interlayer Dielectric (ILD) layer
142
is formed by conventional methods. A contact masking pattern (not shown) is formed over the ILD layer
142
in act
178
of the prior art, and the ILD layer is etched in act
180
to form contact holes
143
. A metal
144
is deposited over the ILD layer
142
in act
182
, thereby filling the contact holes
143
, and the metal is subsequently planarized in act
184
. A wiring layer
145
in then formed over the contact holes
143
to interconnect the capacitor
105
to other devices (not shown) on the semiconductor substrate
110
.
Due to the prior art method
150
utilizing a TiN layer
135
for a top plate
140
of the capacitor
105
, the TiN etching performed in act
174
is critical, since the etch must stop at the semiconductor substrate
110
in order to avoid pitting of the semiconductor substrate. The etch must also be sufficient enough, however, to remove the TiN layer
135
residing over the silicide layer
125
in order to avoid stringers, (i.e., un-etched TiN residing on the suicide layer), which could potentially cause leakage in operation of the capacitor
105
. Accordingly, the TiN etch process of act
174
must be monitored closely in order to avoid the deleterious effects of both over-etching into the semiconductor substrate
110
as well as under-etching the TiN layer
135
. Furthermore, the step
127
of
FIG. 1A
caused by the formation of the polysilicon layer
120
over a non-planar surface of the substrate
110
accentuates the difficulty of the TiN etch when LOCOS is utilized in forming the F
OX
.
SUMMARY OF THE INVENTION
The following presents a simplified summary of the invention in order to provide a basic understanding of some aspects of the invention. This summary is not an extensive overview of the invention. It is intended to neither identify key or critical elements of the invention nor delineate the scope of the invention. Its purpose is to present some concepts of the invention in a simplified form as a prelude to the more detailed description that is presented later.
The present invention relates generally to a method of forming an analog capacitor on a semiconductor substrate. More particularly, the invention relates to a method of forming a high precision analog capacitor over a field oxide (F
OX
) on a semiconductor substrate. According to the present invention, a field oxide layer is formed over a portion of the substrate. A polysilicon layer is formed over the field oxide layer, thereby defining a bottom plate of the capacitor, and a silicide is formed over the polysilicon layer, thereby defining a bottom plate of the capacitor. A first interlayer dielectric (ILD) layer is then formed over the substrate. According to one exemplary aspect of the invention, the first ILD layer comprises a plurality of layers.
Following the formation of the first ILD layer, a capacitor masking pattern is formed over the substrate, and

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