Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Processes of preparing a desired or intentional composition...
Reexamination Certificate
2000-08-28
2003-02-04
Cain, Edward J. (Department: 1714)
Synthetic resins or natural rubbers -- part of the class 520 ser
Synthetic resins
Processes of preparing a desired or intentional composition...
C524S147000, C524S145000, C524S493000, C524S127000
Reexamination Certificate
active
06515053
ABSTRACT:
BACKGROUND OF THE INVENTION
Lead bearing paints have been used for many years at industrial and residential buildings prior to the USEPA ban of such use due to health based concerns over inhalation, ingestion and dermal exposure by children. Lead has been linked to neurotoxic effects in developing infants and children.
Given current demolition in the United States of buildings that contain leaded paint, and the desire of building owners to avoid expensive RCRA lead remedial costs upon demolition of the building and subsequent TCLP lead hazardous waste production, it would be desirable to develop a simple and low cost method for containing lead during building demolition. Methods have been developed to treat lead paint.
SUMMARY OF THE INVENTION
The invention pertains to latex-based compositions and to methods of their use for stabilizing heavy metal on a surface having heavy metal containing paint thereon. A latex based composition comprising a phosphate stabilizing agent and a slipping agent suspended in a latex, such as a latex-based paint, is applied onto a heavy metal containing painted surface before the heavy metal containing paint is removed. The paint can then be removed by mechanical means to produce paint waste in which the heavy metal is complexed to the phosphate stabilizing agent when exposed to natural or induced leaching conditions. The leachability of the heavy metal is reduced such that the paint waste can pass the TCLP, California citric acid leaching test or other leaching test.
In one embodiment, the invention provides a method for reducing heavy metal leaching under natural or induced leaching conditions, from a painted surface containing heavy metal, comprising: applying, onto a surface having painted thereon a heavy metal containing paint, a composition comprising latex based paint, a slipping agent and a phosphate stabilizing agent, wherein the phosphate stabilizing agent binds to the heavy metal to form a heavy metal complex when exposed to natural or induced leaching conditions thereby reducing leaching of the heavy metal from the painted surface. Preferably the stabilizing agent is dicalcium phosphate, tricalcium phosphate or combination thereof.
In another embodiment, the invention provides A method for in situ heavy metal stabilization of heavy metal painted surfaces prior to its creation into waste comprising: a) apply a composition onto a painted surface containing heavy metal; wherein the composition comprising latex based paint, slipping agent and a phosphate stabilizing agent; and b) converting the heavy metal stabilized painted surface into a waste, wherein paint layers exposed are contacted with excess composition.
In yet another embodiment, the invention pertains to a method for producing a sprayable composition for reducing heavy metal leaching, under natural or induced conditions, from a heavy metal painted surface containing, comprising incorporating a phosphate stabilizing agent that substantially maintains the latex paint's adhesive and flowability character, and a slipping agent in an amount sufficient to provide a sprayable viscosity into a latex-based paint to form a sprayable composition.
The invention further provides a latex based paint composition suitable for use in stabilizing lead when coated on a lead containing paint, comprising latex based paint, slipping agent and a phosphate stabilizing agent that substantially maintains the latex paint adhesive and flowability character.
The invention has several advantages. Buildings and other structures containing lead paint, for example, can be treated with the compositions of this invention prior to their demolition or deleading. The methods sufficiently stabilize the heavy metal in the paint waste even as debris from demolition. The methods are easy and have significant economic advantage over other methods currently used to dispose of heavy metal containing paint on buildings slated for demolition. No methods are required to remove the heavy metal containing paint prior to demolition and no RCRA permitting is required for hazardous treatment or handling of the paint waste.
DETAILED DESCRIPTION OF THE INVENTION
It has been discovered that heavy metal in paints can be stabilized in situ by incorporating a phosphate stabilizing agent and slipping agent into a latex-based paint. The latex-based paint can be applied onto a painted surface, whereby the stabilizing agent reacts with the heavy metal to produce a complex that has reduced leachability under natural, acidic or induced leaching conditions. Any surface that can be painted can be treated according to the methods of this invention, such as, but not limited to, bricks, steel, wood, plaster, dry wall and cement. This coating preparation can be applied to any surface coated with lead paint. Specifically, it can be used for outdoor surfaces of building, bridges, industrial machinery, petroleum tanks and the like. Additionally, it can be used on indoor surfaces such as walls, floors and ceiling of homes or businesses.
The invention can be used to stabilize lead, for example, in a building, bridge, boat or other structure that contains heavy metal containing paint. The invention is particularly suited for lead stabilization prior to demolition of the building, bridge, boat or other structure. This process is referred to herein as an in situ stabilization process as the lead is stabilized upon application to the painted surface and as the undercoated paint layers become exposed, such as during demolition. It is not necessary to first remove the heavy metal containing paint from the structure prior to its treatment/stabilization. The process should provide a sufficient amount of stabilizing agent to the heavy metal containing paint, such that even untreated surfaces exposed by demolition are stabilized. Once treated, the heavy metal containing paint will resist leaching of lead and other metals in the paint, such as, but not limited to, copper, zinc, cadmium, nickel, barium, chromium and combinations of these.
The amount of latex-based paint applied to a surface to be treated should be sufficient to provide enough stabilizing agent to complex with the heavy metal contained in the paint to reduce heavy metal leaching under natural or induced leaching conditions, such as, but not limited to, the toxicity characteristic leaching procedure as set forth in the Federal Register, Vol. 55, No. 61 (Mar. 29, 1990) and which corresponds in pertinent part to the procedure set forth in the Federal Register, Vol. 55, No. 126, pp 26985-26998 (Jun. 29, 1990). Preferably two coats of latex-based paint will be applied to the surface. While not intending to be bound by theory, it is believed that the first coating layer stabilizes heavy metals on the surface and the second coating layer provides excess phosphate that is available for treating heavy metal on surfaces that are exposed upon demolition. When the coating is subjected to leaching conditions, e.g., rainwater or TCLP, the phosphate is solubilized and is redistributed (or seeded) to the heavy metal containing surfaces that were not treated, i.e., those surfaces exposed by demolition. Lead containing debris treated according to the methods of the invention passed TCLP. See Examples.
The latex paint used herein can be formulated from any commercially available latex-based paint. Examples of suitable phosphate stabilizing agents include, but are not limited to, phosphate powdered apatites, such as dicalcium phosphate, tricalcium phosphate, coproduct (from aluminum rinse washing, e.g., sulfuric acid, phosphoric acid and aluminum), trisodium phosphate and combination thereof. Dicalcium phosphate (DCP) and tricalcium phosphate (TCP) are preferred, with tricalcium phosphate such as food grade tricalcium phosphate in powdered form being most preferred. It is desirable to select a phosphate stabilizing agent that has a neutral or alkaline pH. Phosphate stabilizing agent(s) is/are admixed into a latex-based paint. The amount of the phosphate stabilizing agent should be sufficient to complex with the he
Cain Edward J.
Hamilton Brook Smith & Reynolds P.C.
Wyrozebski Katarzyna
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