Chemistry: electrical current producing apparatus – product – and – Current producing cell – elements – subcombinations and... – Electrode
Reexamination Certificate
2001-06-22
2003-12-02
Gulakowski, Randy (Department: 1745)
Chemistry: electrical current producing apparatus, product, and
Current producing cell, elements, subcombinations and...
Electrode
C429S218100
Reexamination Certificate
active
06656636
ABSTRACT:
BACKGROUND OF THE INVENTION
1. Field of the Invention
The present invention relates generally to an alkaline storage battery such as a nickel-metal hydride battery, a nickel-cadmium battery, or a nickel-zinc battery and a nickel electrode for an alkaline storage battery employed as a positive electrode of such alkaline storage battery and is particularly characterized in that the nickel electrode for an alkaline storage battery formed by applying a paste containing active material particles composed of nickel hydroxide to a conductive substrate and drying said paste is modified to improve charge/discharge cycle performance of the alkaline storage battery under high temperature conditions.
2. Description of the Related Art
An alkaline storage battery such as a nickel-metal hydride battery or a nickel-cadmium battery has conventionally employed as its positive electrode a nickel electrode for an alkaline storage battery in which nickel hydroxide is used as an active material.
Conventionally, in such nickel electrode for an alkaline storage battery, a sintered nickel electrode formed by impregnating with nickel hydroxide as the active material a sintered substrate which is obtained by filling a porous steel sheet and the like as substrate with nickel powder and sintering said substrate has been used because conductivity of the nickel hydroxide used as the active material is low.
However, in such sintered nickel electrode, bond between particles of the nickel powder is weak. Accordingly, the nickel powder drops out easily when the substrate having high degree of porosity is used. Therefore, the maximum porosity of such substrate is 80% in actual conditions, and hence, the substrate is not sufficiently filled with nickel hydroxide as the active material, thus an alkaline storage battery having a large capacity was hardly attained.
Further, in the above-mentioned sintered nickel electrode, substrate including the porous steel sheet is used, thus filling density of the active material is generally small. In addition, a pore diameter of the nickel powder formed by sintering is generally small, for example, not more than 10 &mgr;m. Thus, in filling the substrate with the active material, solution impregnating method in which laborious work is repeatedly performed must be taken, thereby degrading productivity.
Therefore, a paste type nickel electrode for an alkaline storage battery formed by applying a paste which is obtained by mixing the active material particles composed of nickel hydroxide with a aqueous solution of a binding agent such as methyl cellulose to a conductive substrate having the high degree of porosity such as foamed nickel and drying said paste has been used.
In such paste type nickel electrode for an alkaline storage battery, the conductive substrate having the porosity of not less than 95% can be used. Accordingly, the conductive substrate can be filled with a large number of active materials, thus, the alkaline storage battery having the large capacity is attained, and the conductive substrate can be easily filled with active materials thereby improving the productivity.
However, in such paste type nickel electrode for an alkaline storage battery, when the conductive substrate having the high degree of porosity is used to fill the conductive substrate with the large number of active materials, collecting current of the conductive substrate degrades, thereby reducing the utilization of the active materials.
Therefore, in recent years, in such paste type nickel electrode for an alkaline storage battery, a method in which metal cobalt or a cobalt compound composed of a cobalt oxide or a hydroxide as a conductive agent are added to the above-mentioned active material particles composed of nickel hydroxide, subsequently the above-mentioned metal cobalt and the cobalt compound are oxidized to &bgr;-CoOOH which is cobalt oxyhydroxide by charging, to increase the conductivity of the electrode, thus to improve the utilization of the active materials has been used.
However, even in a case in which the metal cobalt or the cobalt compound as the conductive agent are added to the active material particles composed of nickel hydroxide, there still have remained problems that when the paste type nickel electrode for an alkaline storage battery is employed as the positive electrode of the alkaline storage battery and is charged under high temperature conditions, an oxygen overvoltage in the positive electrode is decreased, thus in addition to a charge reactivity in which nickel hydroxide is oxidized to nickel oxyhydroxide, a side reaction in which an oxygen evolution reactivity occurs and hence, charge characteristics is decreased occur.
Therefore, in Japanese Patent Laid-Open No. Hei8(1996)-222213, in the paste type nickel electrode for an alkaline storage battery, adding a niobium compound and the like in addition to the conductive agent composed of the metal cobalt or the cobalt compound to the surface of the active material particles composed of nickel hydroxide to increase the oxygen overvoltage in the positive electrode by the niobium compound and the like, and hence to improve the charge characteristics under high temperature conditions has been proposed.
However, even in the case where the paste type nickel electrode for an alkaline storage battery in which the niobium compound and the like in addition to the conductive agent composed of the metal cobalt and the cobalt compound are added to the surface of the active material particles composed of nickel hydroxide is used, when charge/discharge is carried out under high temperature conditions, discharge depth during discharge becomes deep, thus cobalt oxyhydroxide which is oxidized metal cobalt or oxidized cobalt compound is reduced to the cobalt hydroxide, then the cobalt hydroxide dissolves in an alkaline electrolyte solution of the alkaline storage battery, subsequently, the cobalt hydroxide deposits on the surface of the active material particles.
A speed in which the cobalt hydroxide dissolves in the alkaline electrolyte solution and deposits as mentioned above is so fast that when the charge and discharge is carried out repeatedly under high temperature conditions, cobalt hydroxide does not deposit on the surface of the active material particles composed of nickel hydroxide uniformly but the cobalt hydroxide segregates on the surface of the active material particles, and a part of the cobalt hydroxide diffuses in the pore, thereby reducing the conductivity of the nickel electrode for an alkaline storage battery gradually, as the result, a charge/discharge cycle performance under high temperature conditions is degraded.
SUMMARY OF THE INVENTION
An object of the present invention is to modify a nickel electrode for an alkaline storage battery formed by applying a paste containing active material particles composed of nickel hydroxide to a conductive substrate and drying said paste.
Another object of the present invention is, in an alkaline storage battery employing as its positive electrode the above-mentioned nickel electrode for an alkaline storage battery, to prevent a discharge capacity from decreasing when charge/discharge is carried out under high temperature conditions, and to improve a charge/discharge cycle performance under high temperature conditions.
The nickel electrode for an alkaline storage battery according to the present invention is a nickel electrode for an alkaline storage battery formed by applying the paste containing the active material particles composed of the nickel hydroxide to the conductive substrate and drying said paste, wherein a conductive layer consisting of cobalt oxide containing sodium is formed on a surface of said active material particles, and niobium powder and/or niobium compound powder is added to the surface of said active material particles.
As the above-mentioned nickel electrode for an alkaline storage battery, when the conductive layer consisting of the cobalt oxide containing sodium is formed on the surface of the active material particles composed of the nickel hydroxi
Ogasawara Takeshi
Tokuda Mitsunori
Yano Mutsumi
Armstrong Westerman & Hattori, LLP
Gulakowski Randy
Sanyo Electronic Co., Ltd.
Wills Monique
LandOfFree
Nickel electrode for alkaline storage battery and alkaline... does not yet have a rating. At this time, there are no reviews or comments for this patent.
If you have personal experience with Nickel electrode for alkaline storage battery and alkaline..., we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Nickel electrode for alkaline storage battery and alkaline... will most certainly appreciate the feedback.
Profile ID: LFUS-PAI-O-3167656