Burying type avalanche photodiode and fabrication method...

Active solid-state devices (e.g. – transistors – solid-state diode – Heterojunction device – Light responsive structure

Reexamination Certificate

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C257S438000

Reexamination Certificate

active

06635908

ABSTRACT:

BACKGROUND OF THE INVENTION
The present invention relates to an avalanche photo-diode and a fabrication method thereof. More particularly the invention pertains to a photo-detector using a semiconductor, and more particularly to a reliable avalanche photo-diode of a mesa structure having a low dark current.
An avalanche photo-diode for use in optical communication and the like is a semiconductor photo-detector whose photo-detecting sensitivity is enhanced by providing a layer for avalanche-multiplying a carrier generated by opto-electronic conversion in addition to an optical absorption region for carrying out opto-electronic conversion. Such an avalanche photo-diode indispensably requires a low dark current and high reliability.
Semiconductor photo-detectors, mostly formed of chemical compound semiconductors, can be broadly classified into planar structure and mesa structure photo-detectors. A mesa structure photo-diode is a diode having a structure in which a mesa is formed over a substrate and the mesa contains a pn junction. The mesa structure, though simple to fabricate, has disadvantages of low reliability and a high dark current. The reasons include the high electric field intensity of the pn junction emerging on a side surface of the mesa, a tendency for electric fields to concentrate on the periphery (edge) of the junction, and that for minute leak current paths to be readily formed by surface state and any surface defect formed on an exposed surface.
On the other hand, a planar structure photo-diode has a structure in which a pn junction region having a high electric field intensity is formed within a crystal, and the part exposed on the surface has a lower electric field intensity, resulting in higher reliability and a lower dark current. However, its fabrication process is complex, sometimes prohibitively difficult depending on the element structure, resulting in a disadvantage of poor practical usefulness.
As a method to alleviate the above-noted disadvantages of mesa-structured semiconductor photo-detectors, a structure to cover the side surface of the mesa with a burying-layer is disclosed in the Japanese Patent Laid-open (Kokai) No. Hei 6-232442. The technique disclosed therein will be described below with reference to FIG.
10
. There is used a process in which, after mesas are formed on layers
82
through
88
crystal-grown over a substrate
81
, a burying-layer
89
of a high-resistance semiconductor is grown over a side surface
90
and a periphery
91
of the mesa. A pn junction surface is formed between the layer
83
and the layer
84
. In addition to them, electrodes
92
and
93
and an anti-reflection layer
94
are formed.
Since the mesa side surface
90
is covered by the burying-layer
89
in this structure, leak currents attributable to the surface state or any surface defect are less than they would be where the burying-layer
89
is absent.
SUMMARY OF THE INVENTION
However, as the electric field intensity around the pn junction emerging on the mesa side surface
90
remains strong in the above-described structure, it is difficult to achieve a low enough dark current or high enough reliability to make the photo-diode adequate for practical use. Especially in an element having a pn junction with a high electric field intensity, such as an avalanche photo-diode, a breakdown (edge breakdown) tends to occur around the junction, inevitably leading to a low rate of multiplication and poor uniformity.
An object of the present invention is to provide a highly reliable mesa-structured avalanche photo-diode using a novel structure capable of keeping the dark current low and a fabrication method therefor.
In order to achieve the above-stated object, an avalanche photo-diode according to the invention has an absorption layer for absorbing light to generate a carrier, a multiplication layer for multiplying the generated carrier, and a field control layer inserted between the absorption layer and the multiplication layer, wherein a first mesa including at least part of the multiplication layer and part of the field control layer is formed over a substrate, a second mesa including another part of the field control layer and the absorption layer is formed over the first mesa, and the area of the top of the first mesa is greater than that of the bottom of the second mesa. A semiconductor layer is formed over the part of the first mesa top surface not covered by the second mesa and the side surface of the second mesa. In the following description, the semiconductor layer will be referred to as the burying-layer.
Further in the avalanche photo-diode, the thickness of the part of the field control layer included in the first mesa is less than the thickness of the field control layer spanning between the first mesa and the second mesa as an additional characteristic.
In the avalanche photo-diode, a semiconductor layer is formed over the part of the first mesa top surface not covered by the second mesa and over the side surface of the second mesa as another additional characteristic. In the following description, if the thickness of the semiconductor layer is large enough to be approximately equal to the height of the second mesa, it will be referred to as a burying-layer, or if it is formed thin for the purpose of protecting the mesa surface, it will be referred to as a semiconductor protection film. It is preferable for this protection film to be a thin film, and to be an insulator or a semiconductor.
A possible structure of a structure avalanche photo-diode according to the invention having the above-stated characteristics will be shown in FIG.
1
. While a more detailed description will be given afterwards, in
FIG. 1
, reference numeral
1
denotes an n-type InP substrate;
2
, an n-type InAlAs buffer layer;
3
, an n-type InAlAs/InGaAs multiplication layer;
4
, a p-type InAlAs field control layer;
5
, a p-type InGaAs absorption layer;
6
, a p-type InAlAs cap layer; and
7
, a p-type InGaAs contact layer.
A pn junction surface is formed on the boundary between the n-type multiplication layer
3
and the p-type field control layer
4
. With the middle plane of the thickness of the field control layer
4
as the border, the layers below that plane constitute a first mesa
18
containing the pn junction while the layers above the constitute a second mesa
13
.
The area of the top of the mesa
18
is greater than the area of the bottom of the mesa
13
. Therefore, the top surface of the mesa
18
has a part not covered by the bottom of the mesa
13
. In the following description, this part will be referred to as the peripheral surface of the second mesa (denoted by a reference numeral
15
in FIG.
1
).
A burying-layer (regrown layer)
8
is formed over a side surface
14
and the peripheral surface
15
of the mesa
13
. The burying-layer
8
, whose carrier concentration is set substantially equal to or below that of the absorption layer
5
, has a high resistance.
The above-described structure can serve to reduce the electric field intensity around the pn junction. The principle of this effect will be explained with reference to FIG.
2
. Electric field designing is essential for an avalanche photo-diode. The electric field intensity distribution in the multiplication layer
3
, the field control layer
4
, the absorption layer
5
in the mesa center represented by a broken line in
FIG. 1
is as represented by a one-dot chain line in FIG.
2
. Thus the electric field intensity is set higher in the multiplication layer
3
to induce avalanche multiplication and, conversely, that in the absorption layer
5
is set lower to avoid avalanche multiplication. Such a electric field intensity distribution can be formed by appropriately regulating the carrier concentration in the field control layer
4
. Incidentally, as the carrier concentration in the cap layer
6
is set substantially higher than that in the absorption layer
5
, no electric field is formed beyond the absorption layer
5
.
Since the electric field intensity in the multiplication layer
3
is extreme

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