Method for fabricating an organic light emitting diode

Semiconductor device manufacturing: process – Making device or circuit emissive of nonelectrical signal – Groove formation

Reexamination Certificate

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Reexamination Certificate

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06582984

ABSTRACT:

CROSS-REFERENCE TO RELATED APPLICATION
This application claims the priority benefit of Taiwan application serial no. 89123457, filed Nov. 7, 2000.
BACKGROUND OF THE INVENTION
1. Field of Invention
The present invention relates to a method for fabricating a light emitting diode. More particularly, the present invention relates to a method for fabricating an organic light emitting diode.
2. Description of Related Art
The organic light emitting diode (OLED) utilizes an emissive characteristic organic film between two electrodes. When the direct currency voltage is charged to the electrodes, a hole will be injected from the anode, and an electron will be injected from the cathode. Because of the potential difference created by the applied voltage, the carrier moves and combines in the thin film, and a part of the electron-hole combines with the electron to release energy that will emit and stimulate the particle, thus forming a single stimulative particle. When the single stimulative particle releases the energy back to the substrate, there is a standard ratio of the energy that is released and radiated by emitting a photon. The above description is that of an organic light emitting diode.
An energy band model is usually used to describe an electric charge movable model. However, because organic material is unlike metal or a semiconductor, it will create a wide energy band. Therefore, the energy band of the organic material actually can form a continuous energy level by the electron-hole. This energy band model can easily explain the procedure after the electric charge injects from the electrode, combines between the energy gaps and emits a photon.
The basic substrate structure of the organic light emitting diode is glass and adds an emissive characteristic organic semiconductor between a metal cathode and a transparency indium-tin-oxide (ITO) anode. More particularly, the carrier can easily reach a balance between the injection and the transportation in the multi-layer structure of the organic semiconductor layer. The structure uses a thin film that includes an electron-hole injected by an electric charge and transmitted to the hole transport layer. The electron-hole combines with the electron and emits light on the emitting layer. The structure also includes a hole injection layer. When the voltage is low, an electron-hole still can be injected into the organic layer.
Accordingly, the color display can be a single color and a multi-color display. If the display is a single color display, it has one emitting layer. If it is a multi-color (red, green and blue, the tricolor) display, it can be formed by a shiftable mask.
FIG. 1
illustrates a conventional structure of an organic light emitting diode. Referring to
FIG. 1
, a glass substrate
100
has a plurality of strip-shaped anodes
110
. On top of the anodes
110
is a multi-layer structure
120
. This multi-layer structure
120
includes a hole injection layer
122
, a hole transport layer
124
, an organic emitting layer
126
and an electron transport layer
128
. On top of the multi-layer structure
120
is a plurality of strip-shaped cathodes
130
.
FIG.
2
A through
FIG. 2D
show the method for fabricating a conventional organic light emitting diode.
Referring to
FIG. 2A
, an indium-tin-oxide (ITO) layer is formed over a glass substrate
200
. Then, using a normal photolithography and etching process, the indium-tin-oxide layer is etched to form a plurality of strip-shaped anodes
210
.
Referring to
FIG. 2B
, a polymer layer
212
is formed between each anode and is used for insulation. In addition, this polymer layer
212
can be flat on the surface of the substrate. But the material of the polymer layer
212
is not very stable and easily changes its shape, so it is does not work well. The polymer layer
212
is an extra coating for the space between the anodes
210
.
Referring to
FIG. 2C
, a multi-layer structure
220
is formed on top of the anode
210
. The multi-layer structure
220
includes a hole injection layer
222
, a hole transport layer
224
, an organic emitting layer
226
and an electron transport layer
228
in sequence. However, the polymer layer
212
is not very smooth; therefore, a multi-layer structure
220
subsequently is formed on an un-smooth surface.
Referring to
FIG. 2D
, the multi-layer structure
220
is covered by a mask, and a plurality of strip-shaped metal are formed to make cathode
230
. The cathode
230
is placed perpendicular to the strip-shaped anode
210
.
In the conventional method for fabricating the organic light emitting diode, the thickness of the anode is greater, and the anode is located on top of the substrate and has a non-flat surface after the process. Although the long strips of the anode and the cathode are insulated by the polymer layer, a cross talk interference problem can still occur.
Therefore, the purpose of this invention is to avoid the non-flat surface of the cathode metal that causes cross talk interference on the organic light emitting diode, which can cause less brightness and instability.
Also, the conventional method uses the polymer to create a smoother surface. This method is costly and also increases the process time. Therefore, this invention does not use a polymer for insulation and flattening, and it also can save time and cost.
SUMMARY OF THE INVENTION
The invention provides a method for fabricating an organic light emitting diode.
As embodied and broadly described herein, the invention provides a substrate and uses a mask to etch the substrate to provide a position for the anode. A plurality of grooves are then formed in the substrate. The anode is formed on the bottom of the groove. A dot-matrix type mask is used to form the organic emitting layer between the anode and the cathode, and to form the hole injection layer, the hole transport layer and the electron transport layer inside the groove. More particularly, the total thickness of the anode, the organic emitting layer, the hole injection layer, the hole transport layer and the electron transport layer is equal to the depth of the groove. Thus, the substrate can have a smooth surface. Finally, another mask is used on the substrate and forms the cathode strips that will complete the fabrication of the organic light emitting diode.
It is to be understood that both the foregoing general description and the following detailed description are exemplary, and are intended to provide further explanation of the invention as claimed.


REFERENCES:
patent: 5242558 (1993-09-01), Matsushima et al.
patent: 5733609 (1998-03-01), Wang
patent: 5847448 (1998-12-01), Val et al.
patent: 5900327 (1999-05-01), Pei et al.
patent: 6010796 (2000-01-01), Kijima
patent: 6057048 (2000-05-01), Hu et al.
patent: 6072517 (2000-06-01), Fork et al.
patent: 40 1-276549 (1989-11-01), None
Derwent Abstracted Publication Number JP401276549A. “Fluroescent Character Display Panel” Takagi et al. Nov. 7, 1989. (Abstract only, corresponds with figures of Japanese application above).*
Dubowski “Laser-based technologies for photonic device integration” Focus on Laser Precision Microfabrication. RIFKEN Review No. 32 (Jan. 2001). Also http://www.riken.go.jp/lab-www/library/publication/review/pdf/No_32/32_047.pdf<visitied Nov. 14, 2002>.

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