Polyaniline derivatives and their production process

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Mixing of two or more solid polymers; mixing of solid...

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Details

525436, 525535, C08G 7100, C08L 7900

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active

058213090

ABSTRACT:
This invention provide a novel cross-linked polyaniline derivative soluble or capable of swelling in general organic solvents, which forms an elastic self-standing film or fibers. The polyaniline derivative substantially comprises a polyaniline having number average molecular weight in a range of from 2,000 to 500,000 represented by the following formula (I) as the main polymer chain, ##STR1## wherein m and n is 0 or an integer of at least 1, m/(m+n)=0-1, and m+n=10-5,000, and cross-linking units represented by the following formula (II) ##STR2## wherein X is a direct bond, a substituted or unsubstituted divalent C.sub.1 -C.sub.30 aliphatic hydrocarbon group, a substituted or unsubstituted divalent aromatic hydrocarbon group, a divalent polysiloxane group or a group derived therefrom, or a divalent group derived from a compound having 2 or more repeating structural unit, Y.sup.1 and Y.sup.2 which may be identical or different denote each a direct bond, ##STR3## wherein Z is an oxygen atom or a sulfur atom, Q is an oxygen atom, a sulfur atom or --NH--, R.sup.1 is a hydrogen atom, a C.sub.1 -C.sub.4 alkyl group, an alkenyl group, an alkoxyl group, a benzyl group or an aryl group, which may be substituted, and a is 0-2.

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