Stock material or miscellaneous articles – Structurally defined web or sheet – Discontinuous or differential coating – impregnation or bond
Reexamination Certificate
2000-07-18
2003-01-07
Kelly, Cynthia H. (Department: 1774)
Stock material or miscellaneous articles
Structurally defined web or sheet
Discontinuous or differential coating, impregnation or bond
C428S206000, C428S212000, C428S313300, C428S323000
Reexamination Certificate
active
06503606
ABSTRACT:
BACKGROUND OF THE INVENTION
1. Field of the Invention
The present invention relates to an ink jet recording sheet which has high ink-absorbance, insures the production of a highly precise image and has high surface strength.
2. Description of the Related Art
The ink jet recording system has many advantageous features such as high speed, low noise and easy multi-colorability and it also enables the production of a large-sized image. Moreover it is characterized in that it is largely flexible to recording patterns and requires neither developing nor fixing. The ink jet system, therefore, become widespread rapidly in various fields as methods enabling the preparation of hard copies of, for example, various figures, including characters, and color images.
In the ink jet recording system, fine liquid droplets of ink are jetted at high speed towards a recording sheet from a nozzle and are stuck to the recording surface to record an image, characters and the like. When the recording sheet has low ink absorbance, the stuck ink is diffused, producing bleeding, which results in the preparation of an unclear image and hence no highly precise image having high resolution is obtained. When the ink-absorbing rate of the recording sheet is low, the sheet cannot deal with image printing of a high speed ink jet printer which has been significantly improved in performance in recent years in addition to the above problems.
In view of this situation, various proposals have been made to improve ink-absorbance and the like. As such an ink jet recording sheet, those containing a silica type pigment and a hydrophilic resin in an ink-receiving layer are proposed.
For example, Japanese Patent Application Lid-Open (JP-A) No. 7-329412 proposes an ink jet recording sheet which is improved in ink-absorbance by using usual silica and a hydrophilic resin in the examples. In the sheet of the example according to this proposal, silica is contained in an amount of 2.5 to 4.5 based on 1 of a resin on a solid weight basis. Since silica is contained in an amount more than 2.5 times the weight of the resin, there is the problem that the sheet has weakened boding strength, causing reduced surface strength.
JP-A No. 8-2091 proposes a recording sheet which is provided with a silica gel layer comprising a silica gel and a polyvinyl alcohol on at least one outermost surface of a substrate to improve the ink-absorbance. In its example, a recording sheet containing a silica gel in an amount ranging from 2.5 to 99.0 based on 1 of a resin on a solid weight basis is proposed. The sheet of the example according to this proposal has the problem that reduced surface strength is caused because it contains silica in an amount 2.5 times the weight of the resin like the sheet proposed in the above JP-A No. 7-329412.
Although the reason why a pigment such as silica is contained in an ink-receiving layer is that it is necessary to improve the absorbance of ink primarily as aforementioned, there is the case where it is contained to increase the opacity at the same time. For instance, an ink jet recording sheet for electric decoration must contain a pigment in an increased amount in an ink-receiving layer to set the opacity to 60 to 85%, specifically, it is necessary that the content of a filler is about 2.5 to 10 based on 1 of a binder resin on a solid weight basis. Even in the case of increasing the opacity like the above, the problem that only insufficient surface strength is obtained is posed when a pigment increases.
As outlined above, such a way as to improve ink-absorbance and to increase the opacity by allowing a large amount of a pigment, e.g., silica, to be contained in an ink-receiving layer causes a reduction in the surface strength. It is therefore necessary to improve the ink-absorbance and to increase the opacity by a method other than the above methods.
However, ink jet recording sheets which are limited in the amount of a pigment such as silica and provided with the abilities of improving the ink-absorbance and increasing the opacity have not been proposed so far.
SUMMARY OF THE INVENTION
In light of the above problems of the conventional recording sheets, the present invention has an object of providing a new ink jet recording sheet which has excellent ink-absorbance, enables the preparation of a highly precise image and has high surface strength.
The structure of the present invention which has been made for the purpose of solving the above problems is characterized in that, in an ink jet recording sheet comprising an ink-receiving layer, containing, as its major components, a binder resin and a pigment, on at least one surface of a substrate, wherein the pigment component includes a hollow filler using a silica-containing inorganic powder as its outer shell layer.
In the above structure, as the hollow filler, one whose outer shell has a microporous structure with a pore diameter of 5 to 60 nm may be used.
In the invention, the substrate may be made of a light-transmittable plastic film and the opacity of the entire sheet including the ink-receiving layer according to JIS-P8138 is made to be 60 to 85% whereby the sheet becomes suitable as electric decorative paper.
Specifically, the inventors of the present invention have made earnest studies and, as a result, found that the inclusion of a silica-containing porous inorganic hollow filler in an ink-receiving layer ensures that an increase in the ink-absorbing capacity which cannot be attained by conventional silica can be made and the promotion of the ink-absorbing capacity can be easily attained since the outer shell layer of the hollow filler has a microporous structure, with the result that, as a whole, the ink-absorbance can be improved. Moreover, the inventors have also found that since the above function can be developed by allowing the hollow filler to be contained only in a small amount, the surface strength is improved and even if the hollow filler is contained in a small amount, sufficient masking ability can be obtained. The present invention has been thus completed.
DESCRIPTION OF THE PREFERRED EMBODIMENTS
An embodiment of the ink jet recording sheet of the present invention will be hereinafter explained.
The recording sheet of the present invention has a structure in which an ink-receiving layer is provided on at least one surface of a substrate as described below. An anchor coat layer may be optionally disposed between the substrate and the ink-receiving layer.
As the substrate constituting the recording sheet of the present invention, paper or a plastic film may be used. As the paper, wood-free paper, mid-quality paper, woody paper, imitation paper, art paper, micro-coated paper, tissue paper, chemical pulp paper or fancy paper may be used. As the plastic film, a film of a general thermoplastic resin such as a polyethylene terephthalate (PET), polypropylene, polystyrene or polycarbonate, a foam film of each of these resins including an inorganic powder such as calcium carbonate or a white PET film including titanium oxide and having surface glossiness may be used. As a substrate used, particularly, for electric decorative paper, a light-transmittable plastic film, e.g., a transparent polyester film and a transparent polypropylene film which are commercially available in general, may be used. Among these films, a polyester film is preferably used in view of rigidity and the like.
Next, the ink-receiving layer to be disposed on the substrate includes a binder resin and a pigment as its major components. A cationic compound may be added to the ink-receiving layer as required. The thickness of the ink-receiving layer is 10 to 60 &mgr;m and preferably 20 to 50 &mgr;m in terms of dry film thickness. When the thickness is 10 &mgr;m or more, no bleeding of ink occurs whereas when the thickness is 60 &mgr;m or less, sufficient surface strength can be obtained.
A hollow filler provided with an outer layer made of a silica-containing inorganic powder is contained in a pigment component of the ink-receiving layer. This inorganic follow filler is a particle having
Nakamura Atsushi
Sato Kazuo
Kelly Cynthia H.
Nisshinbo Industries Inc.
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